Spectroscopic characterization of different structural forms of the new promising energetic material FOX-7 in different solvents

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00437239" target="_blank" >RIV/61388955:_____/15:00437239 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.molstruc.2014.11.014" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2014.11.014</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2014.11.014" target="_blank" >10.1016/j.molstruc.2014.11.014</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Spectroscopic characterization of different structural forms of the new promising energetic material FOX-7 in different solvents

Popis výsledku v původním jazyce

UV?vis, IR and NMR spectroscopy were utilized as direct monitoring techniques for structure changes of a new promising energetic material FOX-7 in different protic and aprotic solvents. The dissolved FOX-7 indicates changes in molecular structure as compared with that in solid-state. The push?pull properties of the molecule together with the effects of solvents result in charge separated zwitterion formed in solution. By combination of different spectroscopic techniques, structural changes of charge-separated molecule of FOX-7 were described in dependence on the solvent properties, temperature, proton activity and concentration. From the analytical point of view, the lowest detectable concentration of FOX-7 using UV? vis spectra was determined to approximately 6 x 10-7 mol L-1.

Název v anglickém jazyce

Spectroscopic characterization of different structural forms of the new promising energetic material FOX-7 in different solvents

Popis výsledku anglicky

UV?vis, IR and NMR spectroscopy were utilized as direct monitoring techniques for structure changes of a new promising energetic material FOX-7 in different protic and aprotic solvents. The dissolved FOX-7 indicates changes in molecular structure as compared with that in solid-state. The push?pull properties of the molecule together with the effects of solvents result in charge separated zwitterion formed in solution. By combination of different spectroscopic techniques, structural changes of charge-separated molecule of FOX-7 were described in dependence on the solvent properties, temperature, proton activity and concentration. From the analytical point of view, the lowest detectable concentration of FOX-7 using UV? vis spectra was determined to approximately 6 x 10-7 mol L-1.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CG - Elektrochemie

OECD FORD obor

—

Projekt

<a href="/cs/project/GA13-21704S" target="_blank" >GA13-21704S: Elektrochemicky aktivní kalix[4]areny a jejich využití pro přípravu nových receptorů a (bio)senzorů</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Svazek periodika

1083

Číslo periodika v rámci svazku

MAR 2015

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

7

Strana od-do

10-16

Kód UT WoS článku

000348879500002

EID výsledku v databázi Scopus

2-s2.0-84919340434