Product ion distributions for the reactions of NO+ with some N-containing and O-containing heterocyclic compounds obtained using SRI-TOF-MS

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00452355" target="_blank" >RIV/61388955:_____/15:00452355 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.ijms.2015.06.003" target="_blank" >http://dx.doi.org/10.1016/j.ijms.2015.06.003</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ijms.2015.06.003" target="_blank" >10.1016/j.ijms.2015.06.003</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Product ion distributions for the reactions of NO+ with some N-containing and O-containing heterocyclic compounds obtained using SRI-TOF-MS

Popis výsledku v původním jazyce

Product ion distributions for the reactions of NO+ with nine O-containing and six N-containing heterocyclic compounds present in human volatilome have been determined under the conditions of a Selective Reagent Ionization Time of Flight Mass Spectrometer(SRI-TOF-MS) at E/N values in the drift tube reactor ranging from 90 to 130Td. This study was undertaken to provide the kinetics data by which these heterocyclic compounds could be analyzed in biogenic media using SRI-TOF-MS. The specific heterocyclic compounds are furan, 2-methylfuran, 3 -methylfuran, 2,5-dimethylfuran, 2-pentylfuran, 2,3-dihydrofuran, 1,3-dioxolane, 2-methyl-1,3-dioxolane, gamma-butyrolactone, pyrrole, 1-methylpyrrole, pyridine, 2,6-dimethylpyridine, pyrimidine, and 4-methylpyrimidine. Charge transfer was the dominant mechanism in the majority of these NO+ reactions generating the respective M+ parent cation, but in the pyridine, pyrimidine, and 4-methylpyrimidine reactions, stable NO+M adduct ions were the major pro

Název v anglickém jazyce

Product ion distributions for the reactions of NO+ with some N-containing and O-containing heterocyclic compounds obtained using SRI-TOF-MS

Popis výsledku anglicky

Product ion distributions for the reactions of NO+ with nine O-containing and six N-containing heterocyclic compounds present in human volatilome have been determined under the conditions of a Selective Reagent Ionization Time of Flight Mass Spectrometer(SRI-TOF-MS) at E/N values in the drift tube reactor ranging from 90 to 130Td. This study was undertaken to provide the kinetics data by which these heterocyclic compounds could be analyzed in biogenic media using SRI-TOF-MS. The specific heterocyclic compounds are furan, 2-methylfuran, 3 -methylfuran, 2,5-dimethylfuran, 2-pentylfuran, 2,3-dihydrofuran, 1,3-dioxolane, 2-methyl-1,3-dioxolane, gamma-butyrolactone, pyrrole, 1-methylpyrrole, pyridine, 2,6-dimethylpyridine, pyrimidine, and 4-methylpyrimidine. Charge transfer was the dominant mechanism in the majority of these NO+ reactions generating the respective M+ parent cation, but in the pyridine, pyrimidine, and 4-methylpyrimidine reactions, stable NO+M adduct ions were the major pro

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

—

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

International Journal of Mass Spectrometry

ISSN

1387-3806

e-ISSN

—

Svazek periodika

386

Číslo periodika v rámci svazku

JUL 2015

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

5

Strana od-do

42-46

Kód UT WoS článku

000361580600007

EID výsledku v databázi Scopus

2-s2.0-84940460556