Copper Bipyridyl Redox Mediators for Dye-Sensitized Solar Cells with High Photovoltage
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F16%3A00466347" target="_blank" >RIV/61388955:_____/16:00466347 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1021/jacs.6b10721" target="_blank" >http://dx.doi.org/10.1021/jacs.6b10721</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jacs.6b10721" target="_blank" >10.1021/jacs.6b10721</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Copper Bipyridyl Redox Mediators for Dye-Sensitized Solar Cells with High Photovoltage
Popis výsledku v původním jazyce
Redox mediators play a major role determining the photocurrent and the photovoltage in dye-sensitized solar cells (DSCs). To maintain the photocurrent, the reduction of oxidized dye by the redox mediator should be significantly faster than the electron back transfer between TiO2 and the oxidized dye. The driving force for dye regeneration with the redox mediator should be sufficiently low to provide high photovoltages. With the introduction of our new copper complexes as promising redox mediators in DSCs both criteria are satisfied to enhance power conversion efficiencies. In this study, two copper bipyridyl complexes, Cu(II/I)(dmby)2TFSI2/1 (0.97 V vs SHE, dmby = 6,6-dimethyl-2,2-bipyridine) and Cu(II/I)(tmby)2TFSI2/1 (0.87 V vs SHE, tmby = 4,4,6,6-tetramethyl-2,2-bipyridine), are presented as new redox couples for DSCs. They are compared to previously reported Cu(II/I)(dmp)2TFSI2/1 (0.93 V vs SHE, dmp = bis(2,9-dimethyl-1,10-phenanthroline). Due to the small reorganization energy between Cu(I) and Cu(II) species, these copper complexes can sufficiently regenerate the oxidized dye molecules with close to unity yield at driving force potentials as low as 0.1 V. The high photovoltages of over 1.0 V were achieved by the series of copper complex based redox mediators without compromising photocurrent densities. Despite the small driving forces for dye regeneration, fast and efficient dye regeneration (2-3 μs) was observed for both complexes. As another advantage, the electron back transfer (recombination) rates were slower with Cu(II/I)(tmby)2TFSI2/1 as evidenced by longer lifetimes. The solar-to-electrical power conversion efficiencies for [Cu(tmby)2]2+/1+, [Cu(dmby)2]2+/1+, and [Cu(dmp)2]2+/1+ based electrolytes were 10.3%, 10.0%, and 10.3%, respectively, using the organic Y123 dye under 1000 W m-2 AM1.5G illumination.
Název v anglickém jazyce
Copper Bipyridyl Redox Mediators for Dye-Sensitized Solar Cells with High Photovoltage
Popis výsledku anglicky
Redox mediators play a major role determining the photocurrent and the photovoltage in dye-sensitized solar cells (DSCs). To maintain the photocurrent, the reduction of oxidized dye by the redox mediator should be significantly faster than the electron back transfer between TiO2 and the oxidized dye. The driving force for dye regeneration with the redox mediator should be sufficiently low to provide high photovoltages. With the introduction of our new copper complexes as promising redox mediators in DSCs both criteria are satisfied to enhance power conversion efficiencies. In this study, two copper bipyridyl complexes, Cu(II/I)(dmby)2TFSI2/1 (0.97 V vs SHE, dmby = 6,6-dimethyl-2,2-bipyridine) and Cu(II/I)(tmby)2TFSI2/1 (0.87 V vs SHE, tmby = 4,4,6,6-tetramethyl-2,2-bipyridine), are presented as new redox couples for DSCs. They are compared to previously reported Cu(II/I)(dmp)2TFSI2/1 (0.93 V vs SHE, dmp = bis(2,9-dimethyl-1,10-phenanthroline). Due to the small reorganization energy between Cu(I) and Cu(II) species, these copper complexes can sufficiently regenerate the oxidized dye molecules with close to unity yield at driving force potentials as low as 0.1 V. The high photovoltages of over 1.0 V were achieved by the series of copper complex based redox mediators without compromising photocurrent densities. Despite the small driving forces for dye regeneration, fast and efficient dye regeneration (2-3 μs) was observed for both complexes. As another advantage, the electron back transfer (recombination) rates were slower with Cu(II/I)(tmby)2TFSI2/1 as evidenced by longer lifetimes. The solar-to-electrical power conversion efficiencies for [Cu(tmby)2]2+/1+, [Cu(dmby)2]2+/1+, and [Cu(dmp)2]2+/1+ based electrolytes were 10.3%, 10.0%, and 10.3%, respectively, using the organic Y123 dye under 1000 W m-2 AM1.5G illumination.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CG - Elektrochemie
OECD FORD obor
—
Návaznosti výsledku
Projekt
<a href="/cs/project/GA13-07724S" target="_blank" >GA13-07724S: Materiálové inženýrství pro inovativní Graetzelovy solární články</a><br>
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2016
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
—
Svazek periodika
138
Číslo periodika v rámci svazku
45
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
10
Strana od-do
15087-15096
Kód UT WoS článku
000388428200040
EID výsledku v databázi Scopus
2-s2.0-84996602423