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Selected ion flow tube study of the reactions of H3O+ and NO+ with a series of primary alcohols in the presence of water vapour in support of selected ion flow tube mass spectrometry

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00484029" target="_blank" >RIV/61388955:_____/17:00484029 - isvavai.cz</a>

  • Výsledek na webu

    <a href="http://dx.doi.org/10.1002/rcm.7811" target="_blank" >http://dx.doi.org/10.1002/rcm.7811</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/rcm.7811" target="_blank" >10.1002/rcm.7811</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Selected ion flow tube study of the reactions of H3O+ and NO+ with a series of primary alcohols in the presence of water vapour in support of selected ion flow tube mass spectrometry

  • Popis výsledku v původním jazyce

    RATIONALE: Alcohols are often present in foods and other biological media, including exhaled breath, urine and cell culture headspace. For their analysis by selected ion flow tube mass spectrometry (SIFT-MS), the ion chemistry initiated by the reactions of the reagent ions H3O+ and NO+ with alcohol molecules in the presence of water molecules needs to be understood and quantitatively described.nMETHODS: The reactions of H3O+ and NO+ ions have been studied with the primary alcohols, methanol, ethanol,n1-propanol, 1-butanol, 1-pentanol and 1-hexanol, under the conditions used for SIFT-MS analyses (1 Torr Hen 0.1 Torrnair sample, 300 K) and over a range of sample gas humidity from 1% to 5.5%.nRESULTS: The H3O+ reactions led to the formation of protonated alcohol molecules MH+ and their hydratesnMH+(H2O)1,2,3 and (MH+-H2O) fragment ions. The NO+ reactions were observed to proceed mainly via hydride ionntransfer, resulting in the formation of [M–H]+ product ions. Formation of the NO+M adduct ions was also observedndue to ligand switching between the NO+(H2O)1,2 hydrated reagent ions and M, and via direct NO+/M association innthe case of ethanol. The variation in the percentages of the hydrated product ions with the air sample humidity is reported.nCONCLUSIONS: This detailed study has provided the kinetics data, including the secondary hydrated ion productndistributions, for the reactions of a number of volatile primary alcohols with the SIFT-MS reagent ions H3O+ and NO+,nwhich allows their analyses by SIFT-MS in humid air and also helps in the interpretation of proton transfer reactionn(PTR)-MS data.

  • Název v anglickém jazyce

    Selected ion flow tube study of the reactions of H3O+ and NO+ with a series of primary alcohols in the presence of water vapour in support of selected ion flow tube mass spectrometry

  • Popis výsledku anglicky

    RATIONALE: Alcohols are often present in foods and other biological media, including exhaled breath, urine and cell culture headspace. For their analysis by selected ion flow tube mass spectrometry (SIFT-MS), the ion chemistry initiated by the reactions of the reagent ions H3O+ and NO+ with alcohol molecules in the presence of water molecules needs to be understood and quantitatively described.nMETHODS: The reactions of H3O+ and NO+ ions have been studied with the primary alcohols, methanol, ethanol,n1-propanol, 1-butanol, 1-pentanol and 1-hexanol, under the conditions used for SIFT-MS analyses (1 Torr Hen 0.1 Torrnair sample, 300 K) and over a range of sample gas humidity from 1% to 5.5%.nRESULTS: The H3O+ reactions led to the formation of protonated alcohol molecules MH+ and their hydratesnMH+(H2O)1,2,3 and (MH+-H2O) fragment ions. The NO+ reactions were observed to proceed mainly via hydride ionntransfer, resulting in the formation of [M–H]+ product ions. Formation of the NO+M adduct ions was also observedndue to ligand switching between the NO+(H2O)1,2 hydrated reagent ions and M, and via direct NO+/M association innthe case of ethanol. The variation in the percentages of the hydrated product ions with the air sample humidity is reported.nCONCLUSIONS: This detailed study has provided the kinetics data, including the secondary hydrated ion productndistributions, for the reactions of a number of volatile primary alcohols with the SIFT-MS reagent ions H3O+ and NO+,nwhich allows their analyses by SIFT-MS in humid air and also helps in the interpretation of proton transfer reactionn(PTR)-MS data.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10403 - Physical chemistry

Návaznosti výsledku

  • Projekt

    Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Ostatní

  • Rok uplatnění

    2017

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Rapid Communications in Mass Spectrometry

  • ISSN

    0951-4198

  • e-ISSN

  • Svazek periodika

    31

  • Číslo periodika v rámci svazku

    5

  • Stát vydavatele periodika

    GB - Spojené království Velké Británie a Severního Irska

  • Počet stran výsledku

    10

  • Strana od-do

    437-446

  • Kód UT WoS článku

    000394512600005

  • EID výsledku v databázi Scopus

    2-s2.0-85011653954