Study of different titanosilicate (TS-1 and ETS-10) as fillers for Mixed Matrix Membranes for CO<inf>2</inf>/CH<inf>4</inf> gas separation applications

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00506651" target="_blank" >RIV/61388955:_____/17:00506651 - isvavai.cz</a>

Výsledek na webu

<a href="http://hdl.handle.net/11104/0297856" target="_blank" >http://hdl.handle.net/11104/0297856</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.memsci.2016.09.041" target="_blank" >10.1016/j.memsci.2016.09.041</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Study of different titanosilicate (TS-1 and ETS-10) as fillers for Mixed Matrix Membranes for CO<inf>2</inf>/CH<inf>4</inf> gas separation applications

Popis výsledku v původním jazyce

Three titanosilicate zeolites were used as fillers for Mixed Matrix Membranes: (i) ETS-10, (ii) TS-1 having Si/Ti=100 and (iii) TS-1 using Si/Ti=25. Zeolite samples were characterized by X-Ray Diffraction, Scanning Electron Microscopy, Atomic Emission Spectroscopy, X-Ray Photoelectron Spectroscopy, and CO2 and CH4 adsorption isotherms. TS-1 particles showed a narrow size distribution ranging from 200 nm to 400 nm. In the case of ETS-10, the size distribution was broader ranging from 400 nm to 800 nm. Mixed Matrix Membranes were prepared using Matrimid® polyimide as continuous phase and filler loadings of 10, 20, and 30 wt%. Membranes were characterized by Thermogravimetric Analysis, Differential Scanning Calorimetry, and Scanning Electron Microscopy. The performances was measured at 8 bars of transmembrane pressure for CO2/CH4 mixed gases system at 50/50 vol/vol. concentration. Membranes using TS-1 (Si/Ti=25) as filler showed a maximum increase of 89.1% of CO2 permeability and 23.9% increase in separation factor. In the case of TS-1 (Si/Ti=100) only permeability increased significantly, with a maximum increase of 90.1%. Regarding the ETS-10 membranes, both permeability and separation factor increased slightly with respect to the reference polymeric membrane (22.5% in CO2 permeability and 7.8% in the separation factor). In conclusion, TS-1 (Si/Ti=25) is the most suitable filler for the use in Mixed Matrix Membranes for gas separation applications among the titanosilicate studied in this work.

Název v anglickém jazyce

Study of different titanosilicate (TS-1 and ETS-10) as fillers for Mixed Matrix Membranes for CO<inf>2</inf>/CH<inf>4</inf> gas separation applications

Popis výsledku anglicky

Three titanosilicate zeolites were used as fillers for Mixed Matrix Membranes: (i) ETS-10, (ii) TS-1 having Si/Ti=100 and (iii) TS-1 using Si/Ti=25. Zeolite samples were characterized by X-Ray Diffraction, Scanning Electron Microscopy, Atomic Emission Spectroscopy, X-Ray Photoelectron Spectroscopy, and CO2 and CH4 adsorption isotherms. TS-1 particles showed a narrow size distribution ranging from 200 nm to 400 nm. In the case of ETS-10, the size distribution was broader ranging from 400 nm to 800 nm. Mixed Matrix Membranes were prepared using Matrimid® polyimide as continuous phase and filler loadings of 10, 20, and 30 wt%. Membranes were characterized by Thermogravimetric Analysis, Differential Scanning Calorimetry, and Scanning Electron Microscopy. The performances was measured at 8 bars of transmembrane pressure for CO2/CH4 mixed gases system at 50/50 vol/vol. concentration. Membranes using TS-1 (Si/Ti=25) as filler showed a maximum increase of 89.1% of CO2 permeability and 23.9% increase in separation factor. In the case of TS-1 (Si/Ti=100) only permeability increased significantly, with a maximum increase of 90.1%. Regarding the ETS-10 membranes, both permeability and separation factor increased slightly with respect to the reference polymeric membrane (22.5% in CO2 permeability and 7.8% in the separation factor). In conclusion, TS-1 (Si/Ti=25) is the most suitable filler for the use in Mixed Matrix Membranes for gas separation applications among the titanosilicate studied in this work.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Membrane Science

ISSN

0376-7388

e-ISSN

—

Svazek periodika

523

Číslo periodika v rámci svazku

FEB 2017

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

12

Strana od-do

24-35

Kód UT WoS článku

000392772900004

EID výsledku v databázi Scopus

2-s2.0-84990990027