An ionic receptor for Zn<sup>2+</sup>metal ion using synthesised bis-formylpyrazole calix[4]arene and its computational study
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00484456" target="_blank" >RIV/61388955:_____/18:00484456 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1080/10610278.2017.1415437" target="_blank" >http://dx.doi.org/10.1080/10610278.2017.1415437</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/10610278.2017.1415437" target="_blank" >10.1080/10610278.2017.1415437</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
An ionic receptor for Zn<sup>2+</sup>metal ion using synthesised bis-formylpyrazole calix[4]arene and its computational study
Popis výsledku v původním jazyce
Newly synthesised receptor Bis-(1,3-diphenyl-pyrazolyl methylene acetohydrazide)Calix[4]arene (DPPMACA) was evaluated for cation binding ability. The receptor DPPMACA selectively interact with Zn 2+ metal ion as assessed through UV-visible spectroscopy with a bathochromic shift of 14 nm but gave negligible response for other metal cations used as their sulfates. The stoichiometry observed as 1:1 with stability constant 6.438 × 10 3 M −1 . Additionally, computational visions were concentrated for studying the stability and spectroscopic analysis of the DPPMACA-Zn 2+ complex using docking, molecular dynamics simulations and density functional theory (DFT) along with time-dependent density functional theory (TD-DFT). The calculations significantly supplement the findings and elucidate the structural geometry and mode of interactions in supramolecular complexation. Herein, we witnessed that DPPMACA was selectively stabilized by Metal-donor and Metal-acceptor contacts with Zn 2+ to generate a low-energy complex. These findings are of wide interest, especially because Zn 2+ is a well-known biological important cation.
Název v anglickém jazyce
An ionic receptor for Zn<sup>2+</sup>metal ion using synthesised bis-formylpyrazole calix[4]arene and its computational study
Popis výsledku anglicky
Newly synthesised receptor Bis-(1,3-diphenyl-pyrazolyl methylene acetohydrazide)Calix[4]arene (DPPMACA) was evaluated for cation binding ability. The receptor DPPMACA selectively interact with Zn 2+ metal ion as assessed through UV-visible spectroscopy with a bathochromic shift of 14 nm but gave negligible response for other metal cations used as their sulfates. The stoichiometry observed as 1:1 with stability constant 6.438 × 10 3 M −1 . Additionally, computational visions were concentrated for studying the stability and spectroscopic analysis of the DPPMACA-Zn 2+ complex using docking, molecular dynamics simulations and density functional theory (DFT) along with time-dependent density functional theory (TD-DFT). The calculations significantly supplement the findings and elucidate the structural geometry and mode of interactions in supramolecular complexation. Herein, we witnessed that DPPMACA was selectively stabilized by Metal-donor and Metal-acceptor contacts with Zn 2+ to generate a low-energy complex. These findings are of wide interest, especially because Zn 2+ is a well-known biological important cation.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10403 - Physical chemistry
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2018
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Supramolecular Chemistry
ISSN
1061-0278
e-ISSN
—
Svazek periodika
30
Číslo periodika v rámci svazku
7
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
11
Strana od-do
589-599
Kód UT WoS článku
000429099200006
EID výsledku v databázi Scopus
2-s2.0-85038398135