Electrochemical characterization of porous boron-doped diamond prepared using SiO2 fiber template

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00489826" target="_blank" >RIV/61388955:_____/18:00489826 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68378271:_____/18:00489826 RIV/68407700:21460/18:00357352

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.diamond.2018.05.007" target="_blank" >http://dx.doi.org/10.1016/j.diamond.2018.05.007</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.diamond.2018.05.007" target="_blank" >10.1016/j.diamond.2018.05.007</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Electrochemical characterization of porous boron-doped diamond prepared using SiO2 fiber template

Popis výsledku v původním jazyce

Porous boron-doped diamond (BDD) is fabricated by consecutive plasma enhanced chemical vapor deposition on a 3D porous SiO2 fiber template deposited by spin coating (SC). The fabricated highly doped and mechanically stable porous BDD layers are characterized by scanning electron microscopy (SEM) and Raman spectroscopy. The roughness factor of the prepared porous BDD, depending on the number of porous layers, was determined from cyclic voltammetry (RFCV) and from krypton adsorption isotherms - BET, (RFBET). Differences in determination of the roughness factor using these two methods are discussed. Electrochemical measurements (cyclic voltammetry and galvanostatic charge/discharge cycling) of porous BDD are performed in aqueous electrolyte solutions with different composition and pH values. The highest electric double-layer capacitance of ca. 2 mu F.cm(-2) , related to the projected geometric (2D) surface area, is obtained for the thickest (26 pm) porous BDD electrode measured in 0.5 M H2SO4 electrolyte solution. The capacitance of the same porous BDD normalized to the total physical surface area (3D) determined by BET is 45 mu F.cm(-2). The electrocatalytic activity of porous BDD electrodes is studied using a hexaammineruthenium(III/II) redox probe, and the electrochemical cycle stability is determined by galvanostatic charge/discharge. The charge retention of the thickest porous BDD samples after removal of non-diamond impurities by an oxidative treatment is ca. 77% after 3000 cycles.

Název v anglickém jazyce

Electrochemical characterization of porous boron-doped diamond prepared using SiO2 fiber template

Popis výsledku anglicky

Porous boron-doped diamond (BDD) is fabricated by consecutive plasma enhanced chemical vapor deposition on a 3D porous SiO2 fiber template deposited by spin coating (SC). The fabricated highly doped and mechanically stable porous BDD layers are characterized by scanning electron microscopy (SEM) and Raman spectroscopy. The roughness factor of the prepared porous BDD, depending on the number of porous layers, was determined from cyclic voltammetry (RFCV) and from krypton adsorption isotherms - BET, (RFBET). Differences in determination of the roughness factor using these two methods are discussed. Electrochemical measurements (cyclic voltammetry and galvanostatic charge/discharge cycling) of porous BDD are performed in aqueous electrolyte solutions with different composition and pH values. The highest electric double-layer capacitance of ca. 2 mu F.cm(-2) , related to the projected geometric (2D) surface area, is obtained for the thickest (26 pm) porous BDD electrode measured in 0.5 M H2SO4 electrolyte solution. The capacitance of the same porous BDD normalized to the total physical surface area (3D) determined by BET is 45 mu F.cm(-2). The electrocatalytic activity of porous BDD electrodes is studied using a hexaammineruthenium(III/II) redox probe, and the electrochemical cycle stability is determined by galvanostatic charge/discharge. The charge retention of the thickest porous BDD samples after removal of non-diamond impurities by an oxidative treatment is ca. 77% after 3000 cycles.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

<a href="/cs/project/GA13-31783S" target="_blank" >GA13-31783S: Studium procesu mezifázového přenosu náboje na borem a fosforem dopovaném diamantu v kontaktu s roztokem elektrolytu</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Diamond and Related Materials

ISSN

0925-9635

e-ISSN

—

Svazek periodika

87

Číslo periodika v rámci svazku

AUG 2018

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

9

Strana od-do

61-69

Kód UT WoS článku

000445294200009

EID výsledku v databázi Scopus

2-s2.0-85048710165