Visualisation and quantification of flooding phenomena in gas diffusion electrodes used for electrochemical CO2 reduction: A combined EDX/ICP–MS approach

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00554826" target="_blank" >RIV/61388955:_____/22:00554826 - isvavai.cz</a>

Výsledek na webu

<a href="http://hdl.handle.net/11104/0329463" target="_blank" >http://hdl.handle.net/11104/0329463</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jcat.2022.02.014" target="_blank" >10.1016/j.jcat.2022.02.014</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Visualisation and quantification of flooding phenomena in gas diffusion electrodes used for electrochemical CO2 reduction: A combined EDX/ICP–MS approach

Popis výsledku v původním jazyce

The most promising strategy to scale up the electrochemical CO2 reduction reaction (ec-CO2RR) is based on the use of gas diffusion electrodes (GDEs) that allow current densities close to the range of 1 A/cm2 to be reached. At such high current densities, however, the flooding of the GDE cathode is often observed in CO2 electrolysers. Flooding hinders the access of CO2 to the catalyst, and by thus leaving space for (unwanted) hydrogen evolution, it usually leads to a decrease of the observable Faradaic efficiency of CO2 reduction products. To avoid flooding as much as possible has thus become one of the most important aims of to-date ec-CO2RR engineering, and robust analytical methods that can quantitatively assess flooding are now in demand. As flooding is very closely related to the formation of carbonate salts within the GDE structure, in this paper we use alkali (in particular, potassium) carbonates as a tracer of flooding. We present a novel analytical approach -based on the combination of cross-sectional energy-dispersive X-ray (EDX) mapping and inductively coupled plasma mass spectrometry (ICP-MS) analysis- that can not only visualise, but can also quantitatively describe the electrolysis time dependent flooding in GDEs, leading to a better understanding of electrolyser malfunctions.

Název v anglickém jazyce

Visualisation and quantification of flooding phenomena in gas diffusion electrodes used for electrochemical CO2 reduction: A combined EDX/ICP–MS approach

Popis výsledku anglicky

The most promising strategy to scale up the electrochemical CO2 reduction reaction (ec-CO2RR) is based on the use of gas diffusion electrodes (GDEs) that allow current densities close to the range of 1 A/cm2 to be reached. At such high current densities, however, the flooding of the GDE cathode is often observed in CO2 electrolysers. Flooding hinders the access of CO2 to the catalyst, and by thus leaving space for (unwanted) hydrogen evolution, it usually leads to a decrease of the observable Faradaic efficiency of CO2 reduction products. To avoid flooding as much as possible has thus become one of the most important aims of to-date ec-CO2RR engineering, and robust analytical methods that can quantitatively assess flooding are now in demand. As flooding is very closely related to the formation of carbonate salts within the GDE structure, in this paper we use alkali (in particular, potassium) carbonates as a tracer of flooding. We present a novel analytical approach -based on the combination of cross-sectional energy-dispersive X-ray (EDX) mapping and inductively coupled plasma mass spectrometry (ICP-MS) analysis- that can not only visualise, but can also quantitatively describe the electrolysis time dependent flooding in GDEs, leading to a better understanding of electrolyser malfunctions.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/GA18-09848S" target="_blank" >GA18-09848S: Fotoelektrochemická redukce oxidu uhličitého na měděných pěnových elektrodách modifikovaných oxidy mědi</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Catalysis

ISSN

0021-9517

e-ISSN

1090-2694

Svazek periodika

408

Číslo periodika v rámci svazku

APR 2022

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

1-8

Kód UT WoS článku

000792492100001

EID výsledku v databázi Scopus

2-s2.0-85125546264