Highly Sensitive Room-Temperature Ammonia Sensors Based on Single-Wall Carbon Nanotubes Modified by PEDOT

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00555107" target="_blank" >RIV/61388955:_____/22:00555107 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/49777513:23220/22:43964879

Výsledek na webu

<a href="https://ieeexplore.ieee.org/document/9678311" target="_blank" >https://ieeexplore.ieee.org/document/9678311</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1109/JSEN.2022.3142405" target="_blank" >10.1109/JSEN.2022.3142405</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Highly Sensitive Room-Temperature Ammonia Sensors Based on Single-Wall Carbon Nanotubes Modified by PEDOT

Popis výsledku v původním jazyce

An ammonia gas sensor material based on sulf- onic functionalized single-wall carbon nanotubes modified by poly(3,4-ethylenedioxythiophene), namely, PEDOT/SWCNT-SO3H, was prepared via in situ polymerization. A thin active layer of PEDOT/SWCNT-SO3H was deposited on a polyimide substrate with interdigital electrodes by air-brush spray coating. The morphology of the prepared material was studied by scanning electron microscopy, and the presence of PEDOT in the structure of SWCNT-SO3H was examined with Raman spectroscopy. The obtained results showed that PEDOT was successfully bound to SWCNT-SO3H and that this modification significantly improved the NH3 sensing performance of the sensor. The sensor exhibited a strong response to ammonia (102% at 50 ppm), minimal drift in the electrical resistance during cyclic exposure, and good spontaneous desorption, all at room temperature. In the range from 20 ppm to 100 ppm ammonia, the calibration curve is considered linear, with a sensitivity of a 0.7% resistance change per 1 ppm ammonia. Furthermore, the sensor shows the ability to detect ammonia at sub-ppm concentration, and the response is 4.4% at 300 ppb. With regard to the material structure, the sensing mechanisms of both materials, i.e., PEDOT/SWCNT-SO3H and SWCNT-SO3H, are discussed in the article.

Název v anglickém jazyce

Highly Sensitive Room-Temperature Ammonia Sensors Based on Single-Wall Carbon Nanotubes Modified by PEDOT

Popis výsledku anglicky

An ammonia gas sensor material based on sulf- onic functionalized single-wall carbon nanotubes modified by poly(3,4-ethylenedioxythiophene), namely, PEDOT/SWCNT-SO3H, was prepared via in situ polymerization. A thin active layer of PEDOT/SWCNT-SO3H was deposited on a polyimide substrate with interdigital electrodes by air-brush spray coating. The morphology of the prepared material was studied by scanning electron microscopy, and the presence of PEDOT in the structure of SWCNT-SO3H was examined with Raman spectroscopy. The obtained results showed that PEDOT was successfully bound to SWCNT-SO3H and that this modification significantly improved the NH3 sensing performance of the sensor. The sensor exhibited a strong response to ammonia (102% at 50 ppm), minimal drift in the electrical resistance during cyclic exposure, and good spontaneous desorption, all at room temperature. In the range from 20 ppm to 100 ppm ammonia, the calibration curve is considered linear, with a sensitivity of a 0.7% resistance change per 1 ppm ammonia. Furthermore, the sensor shows the ability to detect ammonia at sub-ppm concentration, and the response is 4.4% at 300 ppb. With regard to the material structure, the sensing mechanisms of both materials, i.e., PEDOT/SWCNT-SO3H and SWCNT-SO3H, are discussed in the article.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

IEEE Sensors Journal

ISSN

1530-437X

e-ISSN

1558-1748

Svazek periodika

22

Číslo periodika v rámci svazku

4

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

9

Strana od-do

3024-3032

Kód UT WoS článku

000754264700015

EID výsledku v databázi Scopus

2-s2.0-85123368389