Ferrocene Oxidation; a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry

Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F11%3A00439949" target="_blank" >RIV/61388963:_____/11:00439949 - isvavai.cz</a>
Výsledek na webu
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DOI - Digital Object Identifier
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Jazyk výsledku
angličtina
Název v původním jazyce
Ferrocene Oxidation; a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry
Popis výsledku v původním jazyce
The coupling of ESI-MS with two-electrodes flowing cell was provided and tested on ferrocene system. The oxidation potential of ferrocene was 430 mV in Pt/Ag electrode system. The bis-coordinated ferrocene complex with base electrolyte (NaClO4) was foundusing DPASV provided in different accumulation potentials and its analogy was also observed as protonated cation in mass spectra. The impact of inserted accumulation potential on mass spectra was also studied; the inserted potential changes the naturalpattern of ferrocene.
Název v anglickém jazyce
Ferrocene Oxidation; a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry
Popis výsledku anglicky
The coupling of ESI-MS with two-electrodes flowing cell was provided and tested on ferrocene system. The oxidation potential of ferrocene was 430 mV in Pt/Ag electrode system. The bis-coordinated ferrocene complex with base electrolyte (NaClO4) was foundusing DPASV provided in different accumulation potentials and its analogy was also observed as protonated cation in mass spectra. The impact of inserted accumulation potential on mass spectra was also studied; the inserted potential changes the naturalpattern of ferrocene.

Projekt
<a href="/cs/project/GA203%2F08%2F1487" target="_blank" >GA203/08/1487: Mikro-hydratace kationtů kovů v plynné fázi</a><br>
Návaznosti
Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění
2011
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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