Energy partitioning in single-electron transfer events between gaseous dications and their neutral counterparts

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F12%3A00379220" target="_blank" >RIV/61388963:_____/12:00379220 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1255/ejms.1161" target="_blank" >http://dx.doi.org/10.1255/ejms.1161</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1255/ejms.1161" target="_blank" >10.1255/ejms.1161</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Energy partitioning in single-electron transfer events between gaseous dications and their neutral counterparts

Popis výsledku v původním jazyce

Electron-transfer reactions between hydrocarbon dications with neutral hydrocarbons lead to an unequal deposition of the excess energy from the reaction in the pair of monocations formed. The initial observation of this phenomenon was explained by the different states accessible upon single-electron capture by a dication compared to single-electron ejection from a neutral compound. Alternatively, however, isomeric structures of the dicationic species, pronounced Franck-Condon effects, as well as excessenergy in the dicationic precursors could cause the asymmetric energy partitioning in such dication/neutral collisions. Here, the investigation of this phenomenon in an interdisciplinary cooperation is described, shedding light not only upon a possible solution of the problem at hand, but also providing an example for the synergistic benefits of international research networks applying complementary approaches.

Název v anglickém jazyce

Energy partitioning in single-electron transfer events between gaseous dications and their neutral counterparts

Popis výsledku anglicky

Electron-transfer reactions between hydrocarbon dications with neutral hydrocarbons lead to an unequal deposition of the excess energy from the reaction in the pair of monocations formed. The initial observation of this phenomenon was explained by the different states accessible upon single-electron capture by a dication compared to single-electron ejection from a neutral compound. Alternatively, however, isomeric structures of the dicationic species, pronounced Franck-Condon effects, as well as excessenergy in the dicationic precursors could cause the asymmetric energy partitioning in such dication/neutral collisions. Here, the investigation of this phenomenon in an interdisciplinary cooperation is described, shedding light not only upon a possible solution of the problem at hand, but also providing an example for the synergistic benefits of international research networks applying complementary approaches.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA203%2F09%2F1223" target="_blank" >GA203/09/1223: Chemické reakce uhlovodíkových dikationtů při zachování dvojnásobného náboje</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Mass Spectrometry

ISSN

1469-0667

e-ISSN

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Svazek periodika

18

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

139-148

Kód UT WoS článku

000305551000006

EID výsledku v databázi Scopus

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