Quantum dissipation driven by electron transfer within a single molecule investigated with atomic force microscopy

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F20%3A00539699" target="_blank" >RIV/61388963:_____/20:00539699 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68378271:_____/20:00539699 RIV/00216208:11320/20:10422737 RIV/61989592:15310/20:73604269 RIV/00216305:26620/20:PU140227

Výsledek na webu

<a href="https://doi.org/10.1038/s41467-020-15054-w" target="_blank" >https://doi.org/10.1038/s41467-020-15054-w</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1038/s41467-020-15054-w" target="_blank" >10.1038/s41467-020-15054-w</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Quantum dissipation driven by electron transfer within a single molecule investigated with atomic force microscopy

Popis výsledku v původním jazyce

Intramolecular charge transfer processes play an important role in many biological, chemical and physical processes including photosynthesis, redox chemical reactions and electron transfer in molecular electronics. These charge transfer processes are frequently influenced by the dynamics of their molecular or atomic environments, and they are accompanied with energy dissipation into this environment. The detailed understanding of such processes is fundamental for their control and possible exploitation in future technological applications. Here we build upon the recent progress in scanning probe microscopy, and demonstrate the control of mixed valence state. We report observation of single electron transfer between two ferrocene redox centers within a single molecule and the detection of energy dissipation associated with the single electron transfer.n

Název v anglickém jazyce

Quantum dissipation driven by electron transfer within a single molecule investigated with atomic force microscopy

Popis výsledku anglicky

Intramolecular charge transfer processes play an important role in many biological, chemical and physical processes including photosynthesis, redox chemical reactions and electron transfer in molecular electronics. These charge transfer processes are frequently influenced by the dynamics of their molecular or atomic environments, and they are accompanied with energy dissipation into this environment. The detailed understanding of such processes is fundamental for their control and possible exploitation in future technological applications. Here we build upon the recent progress in scanning probe microscopy, and demonstrate the control of mixed valence state. We report observation of single electron transfer between two ferrocene redox centers within a single molecule and the detection of energy dissipation associated with the single electron transfer.n

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Nature Communications

ISSN

2041-1723

e-ISSN

—

Svazek periodika

11

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

1-10

Kód UT WoS článku

000563527200001

EID výsledku v databázi Scopus

2-s2.0-85081744651