Tritium hydrogen-isotope exchange with electron-poor tertiary benzenesulfonamide moiety, application in late-stage labeling of T0901317

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F22%3A00552858" target="_blank" >RIV/61388963:_____/22:00552858 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1002/jlcr.3958" target="_blank" >https://doi.org/10.1002/jlcr.3958</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/jlcr.3958" target="_blank" >10.1002/jlcr.3958</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Tritium hydrogen-isotope exchange with electron-poor tertiary benzenesulfonamide moiety, application in late-stage labeling of T0901317

Popis výsledku v původním jazyce

The universal properties of the loosely bound vibrational states of cold hybrid ion-atom systems are probed using a “scaling” approach. This approach is based on the use of numerical relations (a versus Dlast) between the binding energy (Dlast) of the highest vibrational state and the s-wave scattering length (a) obtained by solving the appropriate Schrödinger equations with scaled interaction potentials. The actual probing is accomplished by evaluating the “a versus Dlast” relations for 6Li +2 and 7Li +2 in the ????2Σ+???? ground electronic state using a set of ab initio potential energy curves from the literature. Although these curves provide strongly differing values of a and Dlast, the corresponding “a versus Dlast” relations closely coincide, thus enabling an accurate determination of scattering lengths directly from experimental binding energies and vice versa.

Název v anglickém jazyce

Tritium hydrogen-isotope exchange with electron-poor tertiary benzenesulfonamide moiety, application in late-stage labeling of T0901317

Popis výsledku anglicky

The universal properties of the loosely bound vibrational states of cold hybrid ion-atom systems are probed using a “scaling” approach. This approach is based on the use of numerical relations (a versus Dlast) between the binding energy (Dlast) of the highest vibrational state and the s-wave scattering length (a) obtained by solving the appropriate Schrödinger equations with scaled interaction potentials. The actual probing is accomplished by evaluating the “a versus Dlast” relations for 6Li +2 and 7Li +2 in the ????2Σ+???? ground electronic state using a set of ab initio potential energy curves from the literature. Although these curves provide strongly differing values of a and Dlast, the corresponding “a versus Dlast” relations closely coincide, thus enabling an accurate determination of scattering lengths directly from experimental binding energies and vice versa.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Labelled Compounds and Radiopharmaceuticals

ISSN

0362-4803

e-ISSN

1099-1344

Svazek periodika

65

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

9

Strana od-do

36-44

Kód UT WoS článku

000737418600001

EID výsledku v databázi Scopus

2-s2.0-85122145256