Vibrational circular dichroism beyond solutions

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F25%3A00619767" target="_blank" >RIV/61388963:_____/25:00619767 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1016/j.saa.2025.125839" target="_blank" >https://doi.org/10.1016/j.saa.2025.125839</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.saa.2025.125839" target="_blank" >10.1016/j.saa.2025.125839</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Vibrational circular dichroism beyond solutions

Popis výsledku v původním jazyce

Since the first vibrational circular dichroism (VCD) experiments conducted in the early 1970s, VCD spectroscopy has significantly advanced and firmly established itself in various fields of modern science and technology. For example, it became one of the preferred methods for absolute configuration determination in the pharmaceutical industry. Nevertheless, VCD development and applications have mostly focused on samples in solution, whereas applications to solid-state samples remain relatively rare. Although the first solid-state experiments were performed around the time of VCD discovery, they did not become the mainstream due to considerably more demanding methodological and theoretical challenges. In this review, we take the reader on a journey through some of the applications of VCD spectroscopy to solid-state samples. We look at the field of solid-state VCD from both a historical perspective and a methodological point of view, highlighting the diverse directions explored with this technique. We attempt to categorize all the variety of solid-state VCD experiments undertaken to date. Additionally, we briefly outline the main challenges faced by the field, and provide an overview of the theoretical methodology accompanying the experimental developments. Finally, we conclude our solid-state VCD journey with an outlook on the future prospects of the field.

Název v anglickém jazyce

Vibrational circular dichroism beyond solutions

Popis výsledku anglicky

Since the first vibrational circular dichroism (VCD) experiments conducted in the early 1970s, VCD spectroscopy has significantly advanced and firmly established itself in various fields of modern science and technology. For example, it became one of the preferred methods for absolute configuration determination in the pharmaceutical industry. Nevertheless, VCD development and applications have mostly focused on samples in solution, whereas applications to solid-state samples remain relatively rare. Although the first solid-state experiments were performed around the time of VCD discovery, they did not become the mainstream due to considerably more demanding methodological and theoretical challenges. In this review, we take the reader on a journey through some of the applications of VCD spectroscopy to solid-state samples. We look at the field of solid-state VCD from both a historical perspective and a methodological point of view, highlighting the diverse directions explored with this technique. We attempt to categorize all the variety of solid-state VCD experiments undertaken to date. Additionally, we briefly outline the main challenges faced by the field, and provide an overview of the theoretical methodology accompanying the experimental developments. Finally, we conclude our solid-state VCD journey with an outlook on the future prospects of the field.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/GA24-10558S" target="_blank" >GA24-10558S: Vývoj chirální vibrační spektroskopie pro systémy v tuhém stavu</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy

ISSN

1386-1425

e-ISSN

1873-3557

Svazek periodika

340

Číslo periodika v rámci svazku

November

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

52

Strana od-do

125839

Kód UT WoS článku

001491173800003

EID výsledku v databázi Scopus

2-s2.0-105004566581