Emerging Trends in Advanced Materials for C―S Coupling Reactions: Design Strategies and Future Perspectives

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F25%3A00639584" target="_blank" >RIV/61388963:_____/25:00639584 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1002/smll.202505046" target="_blank" >https://doi.org/10.1002/smll.202505046</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/smll.202505046" target="_blank" >10.1002/smll.202505046</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Emerging Trends in Advanced Materials for C―S Coupling Reactions: Design Strategies and Future Perspectives

Popis výsledku v původním jazyce

The carbon─sulfur (C─S) bond is an essential structural unit in various therapeutic agents, including antibiotics and anticancer drugs. C─S coupling reactions involving organothiols and aryl electrophiles have emerged as a powerful strategy. Recently, C─S coupling using heterogeneous catalysts like metals, metal oxides, and single-atom sites on polymers, 2D materials, and nanoporous metal-organic frameworks (MOFs) has shown promise due to synergistic properties enhancing nanoscale dispersion, stability, activity, recyclability, and control over key textural parameters. This review highlights the design, synthesis, and catalytic behavior of nanomaterials and their supports for C─S coupling reactions. Particular attention is given to a critical evaluation of the emergence of advanced materials, including a comprehensive discussion of the underlying reaction mechanisms and an in-depth analysis of advanced materials to enhance catalytic activity, selectivity, and stability. Furthermore, mechanistic insights derived from density functional theory calculations are discussed to support the rational design and development of efficient and selective catalysts. Finally, recent advancements, emerging trends are summarized, and strategic insights for the design of next-generation catalysts with enhanced efficiency in C─S bond-forming transformations are offered.

Název v anglickém jazyce

Emerging Trends in Advanced Materials for C―S Coupling Reactions: Design Strategies and Future Perspectives

Popis výsledku anglicky

The carbon─sulfur (C─S) bond is an essential structural unit in various therapeutic agents, including antibiotics and anticancer drugs. C─S coupling reactions involving organothiols and aryl electrophiles have emerged as a powerful strategy. Recently, C─S coupling using heterogeneous catalysts like metals, metal oxides, and single-atom sites on polymers, 2D materials, and nanoporous metal-organic frameworks (MOFs) has shown promise due to synergistic properties enhancing nanoscale dispersion, stability, activity, recyclability, and control over key textural parameters. This review highlights the design, synthesis, and catalytic behavior of nanomaterials and their supports for C─S coupling reactions. Particular attention is given to a critical evaluation of the emergence of advanced materials, including a comprehensive discussion of the underlying reaction mechanisms and an in-depth analysis of advanced materials to enhance catalytic activity, selectivity, and stability. Furthermore, mechanistic insights derived from density functional theory calculations are discussed to support the rational design and development of efficient and selective catalysts. Finally, recent advancements, emerging trends are summarized, and strategic insights for the design of next-generation catalysts with enhanced efficiency in C─S bond-forming transformations are offered.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Small

ISSN

1613-6810

e-ISSN

1613-6829

Svazek periodika

21

Číslo periodika v rámci svazku

39

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

24

Strana od-do

e05046

Kód UT WoS článku

001542993900001

EID výsledku v databázi Scopus

2-s2.0-105012220488