Thermal behaviour of titania based materials - Mathematical modeling of emanation thermal analysis results.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F02%3A50023053" target="_blank" >RIV/61388980:_____/02:50023053 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Thermal behaviour of titania based materials - Mathematical modeling of emanation thermal analysis results.

Popis výsledku v původním jazyce

Emanation thermal analysis (ETA) was used in the characterization of microstructure changes during heating of precursors for the titania based materials: hydrous titania, TiO2.nH(2)O (n=0.58) and hydrous titania containing 10% ruthenia, (TiO2)(0.9)(RuO2)(0.1).nH(2)O (n=1.5). The precursors were heated at the constant rate 6 K min(-1) in argon flow in the range 20-1000degreesC. ETA results were compared with the theoretical curves simulating the temperature dependences of radon release rate, E(T). Two mathematical models were used in the simulation. The models considered either subsequent or simultaneous solid state processes (i.e. dehydration, crystallization or phase transition, resp.) during thermal treatment of titania based materials. A good agreement was found between experimental and the simulated ETA curves. The results of ETA were confirmed by XRD patterns of intermediate products of thermal treatment of the precursors.

Název v anglickém jazyce

Thermal behaviour of titania based materials - Mathematical modeling of emanation thermal analysis results.

Popis výsledku anglicky

Emanation thermal analysis (ETA) was used in the characterization of microstructure changes during heating of precursors for the titania based materials: hydrous titania, TiO2.nH(2)O (n=0.58) and hydrous titania containing 10% ruthenia, (TiO2)(0.9)(RuO2)(0.1).nH(2)O (n=1.5). The precursors were heated at the constant rate 6 K min(-1) in argon flow in the range 20-1000degreesC. ETA results were compared with the theoretical curves simulating the temperature dependences of radon release rate, E(T). Two mathematical models were used in the simulation. The models considered either subsequent or simultaneous solid state processes (i.e. dehydration, crystallization or phase transition, resp.) during thermal treatment of titania based materials. A good agreement was found between experimental and the simulated ETA curves. The results of ETA were confirmed by XRD patterns of intermediate products of thermal treatment of the precursors.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA104%2F00%2F1046" target="_blank" >GA104/00/1046: Vývoj mikrostruktury a tvorba nových fází v systému RuO2-TiO2 během ohřevu v různých plynných mediích</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2002

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Thermal Analysis and Calorimetry

ISSN

1418-2874

e-ISSN

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Svazek periodika

67

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

HU - Maďarsko

Počet stran výsledku

10

Strana od-do

63-72

Kód UT WoS článku

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EID výsledku v databázi Scopus

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