Arsacarborane chemistry. The 7,8,9,11-, 7,9,8,10- and 7,8,9,10-isomers of nido-As2C2B7H9 and some of their halogenated derivatives.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F03%3A50033002" target="_blank" >RIV/61388980:_____/03:50033002 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11310/03:12423

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Arsacarborane chemistry. The 7,8,9,11-, 7,9,8,10- and 7,8,9,10-isomers of nido-As2C2B7H9 and some of their halogenated derivatives.

Popis výsledku v původním jazyce

The reaction between arachno-4,6-C2B7H13 (1) and AsCl3 or AsI3 in CH2Cl2 in the presence of PS (PS='proton sponge', 1,8-bis(dimethylamino) naphthalene) resulted in the isolation of the parent, isomeric eleven-vertex nido diarsadicarbaboranes 7,8,9,11-As2C2B7H9 (2) and 7,9,8,10-As2C2B7H9 (3). Isolated were also halogenated derivatives of 2, 3-Cl-7,8,9,11-As2C2B7H8 (3-Cl-2) and 3-I-7,8,9,11-As2C2B7H8 (3-I-2). The presence of Et3N.BH3 in the reaction mixture increased the yield of unsubstituted compounds and suppressed the formation of halogenated species. The reaction between the isomeric carborane arachno-4,5-C2B7H13 (4) and AsCl3 in CH2Cl2 in the presence of PS gave another isomer, nido-7,8,9,10-As2C2B7H9 (5), which was accompanied by small amounts ofits chloroderivative 3-Cl-7,8,9,10-As2C2B7H8 (3-Cl-5) and compound 3. The structure of the iodinated derivative 3-I-2 was determined by an X-ray diffration analysis. Moreover, the structures of all parent compounds and chloroderivatives,

Název v anglickém jazyce

Arsacarborane chemistry. The 7,8,9,11-, 7,9,8,10- and 7,8,9,10-isomers of nido-As2C2B7H9 and some of their halogenated derivatives.

Popis výsledku anglicky

The reaction between arachno-4,6-C2B7H13 (1) and AsCl3 or AsI3 in CH2Cl2 in the presence of PS (PS='proton sponge', 1,8-bis(dimethylamino) naphthalene) resulted in the isolation of the parent, isomeric eleven-vertex nido diarsadicarbaboranes 7,8,9,11-As2C2B7H9 (2) and 7,9,8,10-As2C2B7H9 (3). Isolated were also halogenated derivatives of 2, 3-Cl-7,8,9,11-As2C2B7H8 (3-Cl-2) and 3-I-7,8,9,11-As2C2B7H8 (3-I-2). The presence of Et3N.BH3 in the reaction mixture increased the yield of unsubstituted compounds and suppressed the formation of halogenated species. The reaction between the isomeric carborane arachno-4,5-C2B7H13 (4) and AsCl3 in CH2Cl2 in the presence of PS gave another isomer, nido-7,8,9,10-As2C2B7H9 (5), which was accompanied by small amounts ofits chloroderivative 3-Cl-7,8,9,10-As2C2B7H8 (3-Cl-5) and compound 3. The structure of the iodinated derivative 3-I-2 was determined by an X-ray diffration analysis. Moreover, the structures of all parent compounds and chloroderivatives,

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2003

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Dalton Transactions

ISSN

1477-9226

e-ISSN

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Svazek periodika

N/A

Číslo periodika v rámci svazku

7

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

5

Strana od-do

1332-1336

Kód UT WoS článku

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EID výsledku v databázi Scopus

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