Separation of trivalent actinides and lanthanides from simulated high-level waste using cobalt bis(dicarbollide) ion derivate substituted with diphenyl-N-tert.octyl-carbamoylmethylphosphine oxide

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F12%3A00376235" target="_blank" >RIV/61388980:_____/12:00376235 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1524/ract.2012.1903" target="_blank" >http://dx.doi.org/10.1524/ract.2012.1903</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1524/ract.2012.1903" target="_blank" >10.1524/ract.2012.1903</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Separation of trivalent actinides and lanthanides from simulated high-level waste using cobalt bis(dicarbollide) ion derivate substituted with diphenyl-N-tert.octyl-carbamoylmethylphosphine oxide

Popis výsledku v původním jazyce

A derivative with cobalt bis(dicarbollide)(1) ion covalently bonded with diphenyl-N-tert.octyl-carbamoylmethylphosphine oxide with a formula [(8-Ph2P(O)-CH2C(O)N-t-C8H17-(CH2-CH2O)2-(1,2-C2B9H10)(1´,2´-C2B9H11)-3,3´-Co] (CMPO-COSAN) has been evaluated for actinides(III)/lanthanides(III) separation from high level liquid waste (HLLW) from PUREX reprocessing. The procedures for HLLW treatment by CMPO-COSAN dissolved in low polar mixture of hexylmethylketone and hydrogenated tetrapropylene (HMK/TPH, 1:1) or polar mixture of nitrobenzene/bromoform (NB/BF, 9:1) were proposed. The good separation of Am(III)/Ln(III) from bulk of fission products was achieved. The trivalent radionuclides were effectively stripped from the loaded organic phase by using ammoniumcitrate or solution of ammonium citrate and ammonium diethylenetriamine pentaacetate (DTPA). The co-extraction of some undesirable elements as Zr, Mo, Pd was suppressed using oxalic acid and HEDTA in extraction and a scrub steps. However

Název v anglickém jazyce

Separation of trivalent actinides and lanthanides from simulated high-level waste using cobalt bis(dicarbollide) ion derivate substituted with diphenyl-N-tert.octyl-carbamoylmethylphosphine oxide

Popis výsledku anglicky

A derivative with cobalt bis(dicarbollide)(1) ion covalently bonded with diphenyl-N-tert.octyl-carbamoylmethylphosphine oxide with a formula [(8-Ph2P(O)-CH2C(O)N-t-C8H17-(CH2-CH2O)2-(1,2-C2B9H10)(1´,2´-C2B9H11)-3,3´-Co] (CMPO-COSAN) has been evaluated for actinides(III)/lanthanides(III) separation from high level liquid waste (HLLW) from PUREX reprocessing. The procedures for HLLW treatment by CMPO-COSAN dissolved in low polar mixture of hexylmethylketone and hydrogenated tetrapropylene (HMK/TPH, 1:1) or polar mixture of nitrobenzene/bromoform (NB/BF, 9:1) were proposed. The good separation of Am(III)/Ln(III) from bulk of fission products was achieved. The trivalent radionuclides were effectively stripped from the loaded organic phase by using ammoniumcitrate or solution of ammonium citrate and ammonium diethylenetriamine pentaacetate (DTPA). The co-extraction of some undesirable elements as Zr, Mo, Pd was suppressed using oxalic acid and HEDTA in extraction and a scrub steps. However

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Radiochimica acta

ISSN

0033-8230

e-ISSN

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Svazek periodika

100

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

5

Strana od-do

179-183

Kód UT WoS článku

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EID výsledku v databázi Scopus

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