Temperature and pressure correlation for volume of gas hydrates with crystal structures sI and sII

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388998%3A_____%2F17%3A00474769" target="_blank" >RIV/61388998:_____/17:00474769 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.epj-conferences.org/articles/epjconf/abs/2017/12/epjconf_efm2017_02141/epjconf_efm2017_02141.html" target="_blank" >https://www.epj-conferences.org/articles/epjconf/abs/2017/12/epjconf_efm2017_02141/epjconf_efm2017_02141.html</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1051/epjconf/201714302141" target="_blank" >10.1051/epjconf/201714302141</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Temperature and pressure correlation for volume of gas hydrates with crystal structures sI and sII

Popis výsledku v původním jazyce

The temperature and pressure correlations for the volume of gas hydrates forming crystal structures sI and sII developed in previous study [Fluid Phase Equilib. 427 (2016) 268-281], focused on the modeling of pure gas hydrates relevant in CCS (carbon capture and storage), were revised and modified for the modeling of mixed hydrates in this study. A universal reference state at temperature of 273.15 K and pressure of 1 Pa is used in the new correlation. Coefficients for the thermal expansion together with the reference lattice parameter were simultaneously correlated to both the temperature data and the pressure data for the lattice parameter. A two-stage Levenberg Marquardt algorithm was employed for the parameter optimization. The pressure dependence described in terms of the bulk modulus remained unchanged compared to the original study. A constant value for the bulk modulus B0 = 10 GPa was employed for all selected hydrate formers. The new correlation is in good agreement with the experimental data over wide temperature and pressure ranges from 0 K to 293 K and from 0 to 2000 MPa, respectively. Compared to the original correlation used for the modeling of pure gas hydrates the new correlation provides significantly better agreement with the experimental data for sI hydrates. The results of the new correlation are comparable to the results of the old correlation in case of sII hydrates. In addition, the new correlation is suitable for modeling of mixed hydrates.

Název v anglickém jazyce

Temperature and pressure correlation for volume of gas hydrates with crystal structures sI and sII

Popis výsledku anglicky

The temperature and pressure correlations for the volume of gas hydrates forming crystal structures sI and sII developed in previous study [Fluid Phase Equilib. 427 (2016) 268-281], focused on the modeling of pure gas hydrates relevant in CCS (carbon capture and storage), were revised and modified for the modeling of mixed hydrates in this study. A universal reference state at temperature of 273.15 K and pressure of 1 Pa is used in the new correlation. Coefficients for the thermal expansion together with the reference lattice parameter were simultaneously correlated to both the temperature data and the pressure data for the lattice parameter. A two-stage Levenberg Marquardt algorithm was employed for the parameter optimization. The pressure dependence described in terms of the bulk modulus remained unchanged compared to the original study. A constant value for the bulk modulus B0 = 10 GPa was employed for all selected hydrate formers. The new correlation is in good agreement with the experimental data over wide temperature and pressure ranges from 0 K to 293 K and from 0 to 2000 MPa, respectively. Compared to the original correlation used for the modeling of pure gas hydrates the new correlation provides significantly better agreement with the experimental data for sI hydrates. The results of the new correlation are comparable to the results of the old correlation in case of sII hydrates. In addition, the new correlation is suitable for modeling of mixed hydrates.

Druh

D - Stať ve sborníku

CEP obor

—

OECD FORD obor

20303 - Thermodynamics

Projekt

<a href="/cs/project/GJ15-07129Y" target="_blank" >GJ15-07129Y: Povrchové napětí vody a vodných směsí v rovnovážném a metastabilním stavu</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

EPJ Web of Conferences

ISBN

—

ISSN

2100-014X

e-ISSN

—

Počet stran výsledku

8

Strana od-do

—

Název nakladatele

E D P SCIENCES

Místo vydání

CEDEX

Místo konání akce

Mariánské Lázně

Datum konání akce

15. 11. 2016

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

000407743800143