RESPONSE OF SURFACE MORPHOLOGY IN COBALT-FULLERENE MIXTURE FILMS UPON VARIATION OF THE METAL CONTENT

Kód výsledku v IS VaVaI

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Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

RESPONSE OF SURFACE MORPHOLOGY IN COBALT-FULLERENE MIXTURE FILMS UPON VARIATION OF THE METAL CONTENT

Popis výsledku v původním jazyce

The morphology and roughness of the films show great change around some critical composition x(c) of the mixture film (x(c) approximate to 3). The films with lower Co content (x < 3) is rather smooth and the roughness is rather low. However, if x >= 3, the roughness of the CoxC60 films dramatically increases and sharp protrusions appear on the surface that reflects an important phase transformation in the film structure. The obtained AFM results define the concentration interval of the Co solubility insolid C-60 (x < 3), which was found to be narrower than that evaluated from spectroscopic experiments (see the text). This interval suggests a formation of the Co1C60 and Co2C60 fullerides in the CoxC60 mixtures where the Co atoms occupy the tetrahedralholes in the fullerene lattice. The dramatic change of the surface morphology at x >= 3 reflects the pronounced Co clustering which likely occurs due to numerical filling the octahedral pores. Formation of the protrusions on the surface o

Název v anglickém jazyce

RESPONSE OF SURFACE MORPHOLOGY IN COBALT-FULLERENE MIXTURE FILMS UPON VARIATION OF THE METAL CONTENT

Popis výsledku anglicky

The morphology and roughness of the films show great change around some critical composition x(c) of the mixture film (x(c) approximate to 3). The films with lower Co content (x < 3) is rather smooth and the roughness is rather low. However, if x >= 3, the roughness of the CoxC60 films dramatically increases and sharp protrusions appear on the surface that reflects an important phase transformation in the film structure. The obtained AFM results define the concentration interval of the Co solubility insolid C-60 (x < 3), which was found to be narrower than that evaluated from spectroscopic experiments (see the text). This interval suggests a formation of the Co1C60 and Co2C60 fullerides in the CoxC60 mixtures where the Co atoms occupy the tetrahedralholes in the fullerene lattice. The dramatic change of the surface morphology at x >= 3 reflects the pronounced Co clustering which likely occurs due to numerical filling the octahedral pores. Formation of the protrusions on the surface o

Druh

D - Stať ve sborníku

CEP obor

BM - Fyzika pevných látek a magnetismus

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

NANOCON 2014. 6th International conference proceedings

ISBN

978-80-87294-53-6

ISSN

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e-ISSN

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Počet stran výsledku

6

Strana od-do

109-114

Název nakladatele

TANGER

Místo vydání

Ostrava

Místo konání akce

Brno

Datum konání akce

5. 11. 2014

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

000350636300017