Transport malých molekul přes membrány z polyfenylenoxidu modifikovaného fulereny
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F07%3A00080089" target="_blank" >RIV/61389013:_____/07:00080089 - isvavai.cz</a>
Výsledek na webu
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DOI - Digital Object Identifier
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Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Transport of small molecules through polyphenylene oxide membranes modified by fullerene
Popis výsledku v původním jazyce
Homogeneous membranes based on fullerene-polyphenylene oxide compositions containing up to 2 wt% fullerene C60 were prepared. The effect of fullerene addition on PPO transport properties was studied in gas separation and pervaporation processes. Permeability coefficients of H2, O2, N2, CH4, and CO2 were measured; a correlation between gas transport properties and membrane free volume was established. Pervaporation properties were studied for the system with ethyl acetate synthesis reaction: quaternary system ethanol - acetic acid - water - ethyl acetate and some constituent binary and ternary mixtures. Pervaporation in binary systems, ethanol-water and ethyl acetate-water was considered with the use of the data on sorption capacities and interaction parameters. In pervaporation of a quaternary reacting mixture, the permeate containing essentially ethyl acetate was obtained. Results show that membranes with fullerene additives exhibit improved transport properties.
Název v anglickém jazyce
Transport of small molecules through polyphenylene oxide membranes modified by fullerene
Popis výsledku anglicky
Homogeneous membranes based on fullerene-polyphenylene oxide compositions containing up to 2 wt% fullerene C60 were prepared. The effect of fullerene addition on PPO transport properties was studied in gas separation and pervaporation processes. Permeability coefficients of H2, O2, N2, CH4, and CO2 were measured; a correlation between gas transport properties and membrane free volume was established. Pervaporation properties were studied for the system with ethyl acetate synthesis reaction: quaternary system ethanol - acetic acid - water - ethyl acetate and some constituent binary and ternary mixtures. Pervaporation in binary systems, ethanol-water and ethyl acetate-water was considered with the use of the data on sorption capacities and interaction parameters. In pervaporation of a quaternary reacting mixture, the permeate containing essentially ethyl acetate was obtained. Results show that membranes with fullerene additives exhibit improved transport properties.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CD - Makromolekulární chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
<a href="/cs/project/GA203%2F06%2F1207" target="_blank" >GA203/06/1207: Výroba, separace a skladování biovodíku pro energetiku</a><br>
Návaznosti
Z - Vyzkumny zamer (s odkazem do CEZ)
Ostatní
Rok uplatnění
2007
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Separation Science and Technology
ISSN
0149-6395
e-ISSN
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Svazek periodika
42
Číslo periodika v rámci svazku
2
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
15
Strana od-do
333-347
Kód UT WoS článku
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EID výsledku v databázi Scopus
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