Behavior of tin-based "super-POSS" incorporated in different bonding situations in hybrid epoxy resins

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F14%3A00431040" target="_blank" >RIV/61389013:_____/14:00431040 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1021/ma500507j" target="_blank" >http://dx.doi.org/10.1021/ma500507j</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/ma500507j" target="_blank" >10.1021/ma500507j</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Behavior of tin-based "super-POSS" incorporated in different bonding situations in hybrid epoxy resins

Popis výsledku v původním jazyce

Hybrid organic?inorganic epoxies containing the heavier POSS homologue, n-butylstannoxane dodecamer, incorporated as an inert block, as a linear unit, and as a network junction were prepared. This nanometer-sized inorganic cage is especially attractive because of its chemical reactivity (besides mechanical matrix reinforcement). It can undergo oxidative cross-linking reactions with the matrix, or at elevated temperature in the absence of air, it can oligomerize to larger nanodomains, thus generating additional chemical cross-links. The influences of the bonding situation of the stannoxane cages on the hybrid resins? morphology, mechanical properties, and on the cages? chemical activity were studied.

Název v anglickém jazyce

Behavior of tin-based "super-POSS" incorporated in different bonding situations in hybrid epoxy resins

Popis výsledku anglicky

Hybrid organic?inorganic epoxies containing the heavier POSS homologue, n-butylstannoxane dodecamer, incorporated as an inert block, as a linear unit, and as a network junction were prepared. This nanometer-sized inorganic cage is especially attractive because of its chemical reactivity (besides mechanical matrix reinforcement). It can undergo oxidative cross-linking reactions with the matrix, or at elevated temperature in the absence of air, it can oligomerize to larger nanodomains, thus generating additional chemical cross-links. The influences of the bonding situation of the stannoxane cages on the hybrid resins? morphology, mechanical properties, and on the cages? chemical activity were studied.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GAP108%2F11%2F2151" target="_blank" >GAP108/11/2151: Nové nanokompozitní pryskyřice obsahující funkcionalizované stannoxanové nanočástice</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Macromolecules

ISSN

0024-9297

e-ISSN

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Svazek periodika

47

Číslo periodika v rámci svazku

13

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

22

Strana od-do

4266-4287

Kód UT WoS článku

000338806400016

EID výsledku v databázi Scopus

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