Hydrogen-bonding versus .pi.-.pi. stacking in the design of organic semiconductors: from dyes to oligomers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00442968" target="_blank" >RIV/61389013:_____/15:00442968 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.progpolymsci.2014.10.010" target="_blank" >http://dx.doi.org/10.1016/j.progpolymsci.2014.10.010</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.progpolymsci.2014.10.010" target="_blank" >10.1016/j.progpolymsci.2014.10.010</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Hydrogen-bonding versus .pi.-.pi. stacking in the design of organic semiconductors: from dyes to oligomers

Popis výsledku v původním jazyce

This review discusses some general aspects of the highly directional intermolecular interactions in organic solids, followed by an overview of ?-conjugated systems exhibiting directional preference in the intermolecular connection and demonstrating enhanced energy and/or charge carrier transfer. As examples, ?small dyes and pigments, ?intermediate-sized N-heteroacenes, and ?large hydrogen-bonded oligomers are considered. In all of these systems the intermolecular interactions between polarized peripheries of the ?-conjugated moieties ensure a preferential direction in the molecular packing. The most important among these interactions are hydrogen bonds (both strong and weak). As demonstrated recently, hydrogen bonding represents a dominant attractive force even for molecules with different polarization of the ?-conjugated aromatic or heterocyclic moieties, considered to be the most favorable condition for ?face-to-face orientation (??? stacking). The solid-state anisotropy, most likely

Název v anglickém jazyce

Hydrogen-bonding versus .pi.-.pi. stacking in the design of organic semiconductors: from dyes to oligomers

Popis výsledku anglicky

This review discusses some general aspects of the highly directional intermolecular interactions in organic solids, followed by an overview of ?-conjugated systems exhibiting directional preference in the intermolecular connection and demonstrating enhanced energy and/or charge carrier transfer. As examples, ?small dyes and pigments, ?intermediate-sized N-heteroacenes, and ?large hydrogen-bonded oligomers are considered. In all of these systems the intermolecular interactions between polarized peripheries of the ?-conjugated moieties ensure a preferential direction in the molecular packing. The most important among these interactions are hydrogen bonds (both strong and weak). As demonstrated recently, hydrogen bonding represents a dominant attractive force even for molecules with different polarization of the ?-conjugated aromatic or heterocyclic moieties, considered to be the most favorable condition for ?face-to-face orientation (??? stacking). The solid-state anisotropy, most likely

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

—

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Progress in Polymer Science

ISSN

0079-6700

e-ISSN

—

Svazek periodika

43

Číslo periodika v rámci svazku

April

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

15

Strana od-do

33-47

Kód UT WoS článku

000353007600002

EID výsledku v databázi Scopus

2-s2.0-84939943916