Polypseudorotaxanes between .alpha.-cyclodextrin and poly(propylene glycol)-b-poly(ethylene glycol)-b-poly(propylene glycol) copolymers studied by MALDI-TOF mass spectrometry
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F16%3A00456042" target="_blank" >RIV/61389013:_____/16:00456042 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.eurpolymj.2015.11.037" target="_blank" >http://dx.doi.org/10.1016/j.eurpolymj.2015.11.037</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.eurpolymj.2015.11.037" target="_blank" >10.1016/j.eurpolymj.2015.11.037</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Polypseudorotaxanes between .alpha.-cyclodextrin and poly(propylene glycol)-b-poly(ethylene glycol)-b-poly(propylene glycol) copolymers studied by MALDI-TOF mass spectrometry
Popis výsledku v původním jazyce
MALDI-TOF mass spectrometry is used to show that formation of solid polypseudorotaxanes between α-cyclodextrin (α-CD) and poly(propylene glycol)–poly(ethylene glycol)–poly(propylene glycol) block copolymers (PPG–PEG–PPG, Reverse Pluronics) is a block length selective process. A comparison of copolymer composition matrices of neat Reverse Pluronics 10R5 and 17R4 and of the copolymers in their precipitated complexes with α-CD shows that the distribution with respect to an absolute PPG content is not affected by the complexation, which means that complexation occurs with Reverse Pluronics generally, not just with the fraction of copolymers with at least one outer block short or completely absent and that α-CD can slide even over block of 20 PG. Nevertheless, the complexation is a selective process with respect to PEG as copolymers with shorter PEG blocks are more abundant in the supernatant while the content of PPG remains almost unchanged for both Reverse Pluronics.
Název v anglickém jazyce
Polypseudorotaxanes between .alpha.-cyclodextrin and poly(propylene glycol)-b-poly(ethylene glycol)-b-poly(propylene glycol) copolymers studied by MALDI-TOF mass spectrometry
Popis výsledku anglicky
MALDI-TOF mass spectrometry is used to show that formation of solid polypseudorotaxanes between α-cyclodextrin (α-CD) and poly(propylene glycol)–poly(ethylene glycol)–poly(propylene glycol) block copolymers (PPG–PEG–PPG, Reverse Pluronics) is a block length selective process. A comparison of copolymer composition matrices of neat Reverse Pluronics 10R5 and 17R4 and of the copolymers in their precipitated complexes with α-CD shows that the distribution with respect to an absolute PPG content is not affected by the complexation, which means that complexation occurs with Reverse Pluronics generally, not just with the fraction of copolymers with at least one outer block short or completely absent and that α-CD can slide even over block of 20 PG. Nevertheless, the complexation is a selective process with respect to PEG as copolymers with shorter PEG blocks are more abundant in the supernatant while the content of PPG remains almost unchanged for both Reverse Pluronics.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CD - Makromolekulární chemie
OECD FORD obor
—
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2016
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
European Polymer Journal
ISSN
0014-3057
e-ISSN
—
Svazek periodika
74
Číslo periodika v rámci svazku
January
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
8
Strana od-do
256-263
Kód UT WoS článku
000369204100024
EID výsledku v databázi Scopus
2-s2.0-84949501939