Effect of graphite nanoplatelets on melt drawing and properties of PCL/PLA microfibrillar composites

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F18%3A00493937" target="_blank" >RIV/61389013:_____/18:00493937 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/pc.24322" target="_blank" >http://dx.doi.org/10.1002/pc.24322</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/pc.24322" target="_blank" >10.1002/pc.24322</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Effect of graphite nanoplatelets on melt drawing and properties of PCL/PLA microfibrillar composites

Popis výsledku v původním jazyce

The study deals with upgrading of a poly (epsilon‐caprolactone) (PCL)‐based biodegradable material using graphite nanoplatelets‐aided in‐situ formation of reinforcing microfibers, that is, preparation of a microfibrillar composite (MFC) based on the PCL/poly lactic acid (PLA) 80/20 blend. Recently, we have found that effective melt‐drawing is impossible due to flow instability and that PLA fibrils formation is only possible with addition of high‐aspect‐ratio nanofillers (NF), such as momtmorillonite or halloysite. This work concerns modification of the PCL/PLA blend with graphite nanoplatelets (GNPs). Results indicate that relatively large GNPs excellently support stability of extrusion which leads to better drawability in comparison with other NF. Hence, reinforcement of the components by GNP and fibrils formation accompanied by increased PLA crystallinity lead to a biocompatible and biodegradable material with good performance. Increased PLA crystallinity due to its annealing during subsequent processing and substantial suppression of cold crystallization is another advantage of the MFC concept in the PCL/PLA system.

Název v anglickém jazyce

Effect of graphite nanoplatelets on melt drawing and properties of PCL/PLA microfibrillar composites

Popis výsledku anglicky

The study deals with upgrading of a poly (epsilon‐caprolactone) (PCL)‐based biodegradable material using graphite nanoplatelets‐aided in‐situ formation of reinforcing microfibers, that is, preparation of a microfibrillar composite (MFC) based on the PCL/poly lactic acid (PLA) 80/20 blend. Recently, we have found that effective melt‐drawing is impossible due to flow instability and that PLA fibrils formation is only possible with addition of high‐aspect‐ratio nanofillers (NF), such as momtmorillonite or halloysite. This work concerns modification of the PCL/PLA blend with graphite nanoplatelets (GNPs). Results indicate that relatively large GNPs excellently support stability of extrusion which leads to better drawability in comparison with other NF. Hence, reinforcement of the components by GNP and fibrils formation accompanied by increased PLA crystallinity lead to a biocompatible and biodegradable material with good performance. Increased PLA crystallinity due to its annealing during subsequent processing and substantial suppression of cold crystallization is another advantage of the MFC concept in the PCL/PLA system.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Projekt

<a href="/cs/project/GA13-15255S" target="_blank" >GA13-15255S: In situ polymer-polymer kompozity s cílenou aplikací nanoplniv různých geometrií</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polymer Composites

ISSN

0272-8397

e-ISSN

—

Svazek periodika

39

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

3147-3156

Kód UT WoS článku

000445738400019

EID výsledku v databázi Scopus

2-s2.0-85013667643