Evaluation of the glycerolysis process and valorisation of recovered polyol in polyurethane synthesis

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F19%3A00503740" target="_blank" >RIV/61389013:_____/19:00503740 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S1381514818310885?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1381514818310885?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.reactfunctpolym.2019.03.012" target="_blank" >10.1016/j.reactfunctpolym.2019.03.012</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Evaluation of the glycerolysis process and valorisation of recovered polyol in polyurethane synthesis

Popis výsledku v původním jazyce

In this study, the glycerolysis of polyurethane (PU) foam and the applicability of obtained glycerolysate (GLY) for cast PUs were investigated. It was found that crude glycerine with purity grade of 84% might be successfully used for the glycerolysis. The optimal conditions were determined as follows: reaction time of 60 min at 220 °C using dibutyltin dilaurate catalyst (0.5%). Moreover, the purification of GLY by means of liquid-liquid extraction and distillation was also adapted. nCast PUs based on GLY were prepared using a two-step method, during which a prepolymer was first synthesised from a mixture of virgin polyol, GLY and 4, 4′-diphenylmethane diisocyanate (MDI). The prepolymer was then extended with a chain extender, 1, 4-butanediol or 1, 3-propanediol. The effect of virgin polyol replacement by GLY (up to 75%) on thermal and mechanical properties of the cast PUs was determined. The PUs based on GLY exhibited slightly lower thermal stability, higher storage modulus and higher glass transition temperature than the neat PU. The tensile strength of all prepared PUs was beneficially high (12–15 MPa), while the elongation at break decreased with the increasing GLY content probable due to the branching of PU chains.

Název v anglickém jazyce

Evaluation of the glycerolysis process and valorisation of recovered polyol in polyurethane synthesis

Popis výsledku anglicky

In this study, the glycerolysis of polyurethane (PU) foam and the applicability of obtained glycerolysate (GLY) for cast PUs were investigated. It was found that crude glycerine with purity grade of 84% might be successfully used for the glycerolysis. The optimal conditions were determined as follows: reaction time of 60 min at 220 °C using dibutyltin dilaurate catalyst (0.5%). Moreover, the purification of GLY by means of liquid-liquid extraction and distillation was also adapted. nCast PUs based on GLY were prepared using a two-step method, during which a prepolymer was first synthesised from a mixture of virgin polyol, GLY and 4, 4′-diphenylmethane diisocyanate (MDI). The prepolymer was then extended with a chain extender, 1, 4-butanediol or 1, 3-propanediol. The effect of virgin polyol replacement by GLY (up to 75%) on thermal and mechanical properties of the cast PUs was determined. The PUs based on GLY exhibited slightly lower thermal stability, higher storage modulus and higher glass transition temperature than the neat PU. The tensile strength of all prepared PUs was beneficially high (12–15 MPa), while the elongation at break decreased with the increasing GLY content probable due to the branching of PU chains.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

<a href="/cs/project/LO1507" target="_blank" >LO1507: Polymery pro pokročilé technologie i kvalitnější život</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Reactive and Functional Polymers

ISSN

1381-5148

e-ISSN

—

Svazek periodika

139

Číslo periodika v rámci svazku

June

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

25-33

Kód UT WoS článku

000469905900004

EID výsledku v databázi Scopus

2-s2.0-85063109865