Kinetics of pozzolanic reaction and carbonation in ceramic - lime system: thermogravimetry and solid-state NMR spectroscopy study

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F20%3A00532476" target="_blank" >RIV/61389013:_____/20:00532476 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68407700:21110/20:00343449 RIV/68407700:21720/20:00343449

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2352710220333623?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352710220333623?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jobe.2020.101729" target="_blank" >10.1016/j.jobe.2020.101729</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Kinetics of pozzolanic reaction and carbonation in ceramic - lime system: thermogravimetry and solid-state NMR spectroscopy study

Popis výsledku v původním jazyce

Waste red-clay ceramic powder (RCC) is a pozzolanic material which is currently not commercially used, but high amount of “brick fraction” of construction and demolition waste may become a source for a cheap pozzolanic additive for Portland cement and lime-based binders. A sort of specific of RCC, compared to other pozzolans, is the higher content of non-reactive minerals. Pozzolanic reaction, taking place in lime-based system, is inevitably accompanied by carbonation of the lime. These two processes are concurrent with respect to the lime consumption. Products of hydration (C–S–H and calcium aluminate hydrate phases) and carbonation (CaCO3) are contributing to the strengthening of the system. The goal of this research has been to evaluate the rate and mechanism of hardening of the RCC – lime mixtures. The relative rate of pozzolanic reaction and carbonation was studied over one-year period in RCC – lime pastes by help of thermal analysis and 23Na, 27Al and 29Si Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy (MAS NMR), accompanied by porosimetry and compressive strength determination. The kinetics of lime conversion to hydration products and CaCO3 was determined by the help of thermogravimetry and described by Jander's equation. The highest rate of pozzolanic reaction, as well as the highest strength, reached mixture of 70% of RCC and 30% of lime, such high effective pozzolana content is caused by the phase composition of ceramic powder – it contains lower amount of reactive species, compared to metakaolin or other pozzolans. The formation of AlVI hydration products (AFm and AFt phases) took place within initial 3 days in all mixtures, while the content of C–S–H hydrates grown over the whole year of the experiment.

Název v anglickém jazyce

Kinetics of pozzolanic reaction and carbonation in ceramic - lime system: thermogravimetry and solid-state NMR spectroscopy study

Popis výsledku anglicky

Waste red-clay ceramic powder (RCC) is a pozzolanic material which is currently not commercially used, but high amount of “brick fraction” of construction and demolition waste may become a source for a cheap pozzolanic additive for Portland cement and lime-based binders. A sort of specific of RCC, compared to other pozzolans, is the higher content of non-reactive minerals. Pozzolanic reaction, taking place in lime-based system, is inevitably accompanied by carbonation of the lime. These two processes are concurrent with respect to the lime consumption. Products of hydration (C–S–H and calcium aluminate hydrate phases) and carbonation (CaCO3) are contributing to the strengthening of the system. The goal of this research has been to evaluate the rate and mechanism of hardening of the RCC – lime mixtures. The relative rate of pozzolanic reaction and carbonation was studied over one-year period in RCC – lime pastes by help of thermal analysis and 23Na, 27Al and 29Si Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy (MAS NMR), accompanied by porosimetry and compressive strength determination. The kinetics of lime conversion to hydration products and CaCO3 was determined by the help of thermogravimetry and described by Jander's equation. The highest rate of pozzolanic reaction, as well as the highest strength, reached mixture of 70% of RCC and 30% of lime, such high effective pozzolana content is caused by the phase composition of ceramic powder – it contains lower amount of reactive species, compared to metakaolin or other pozzolans. The formation of AlVI hydration products (AFm and AFt phases) took place within initial 3 days in all mixtures, while the content of C–S–H hydrates grown over the whole year of the experiment.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

<a href="/cs/project/GA18-13525S" target="_blank" >GA18-13525S: Malty moderních mozaik pod drobnohledem - metody pro materiálovou charakterizaci a studium degradace</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Building Engineering

ISSN

2352-7102

e-ISSN

—

Svazek periodika

32

Číslo periodika v rámci svazku

November

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

1-11

Kód UT WoS článku

000588052000175

EID výsledku v databázi Scopus

2-s2.0-85091851563