Novel waterborne poly(urethane‐urea)/silica nanocomposites

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F20%3A00532979" target="_blank" >RIV/61389013:_____/20:00532979 - isvavai.cz</a>

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/10.1002/pc.25690" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/pc.25690</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/pc.25690" target="_blank" >10.1002/pc.25690</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Novel waterborne poly(urethane‐urea)/silica nanocomposites

Popis výsledku v původním jazyce

A series of novel transparent mechanically strong waterborne poly(urethane‐urea)/silica nanocomposites were prepared by mixing a waterborne poly(urethane‐urea) dispersion with aqueous nanosilica, followed by slow water evaporation. This procedure is simple, environmentally friendly and energetically undemanding. The silica content in the nanocomposite film varied from 0 to 50 wt%. Based on changes of tensile characteristics, for example, Young's modulus values, three types of behavior were observed: typical elastic (0‐10 wt%), plastic (30 wt%) and ceramic‐like (50 wt% silica) materials can be prepared. However, some films feature both elastic and plastic (material with 20 wt% silica) or plastic and ceramic‐like characteristics (material with 40 wt% silica). The Young's modulus varied from 6 to 705 MPa, and the maximal tensile strength and elongation‐at‐break were 17.3 MPa and 1270%, respectively. The maximum energy‐to‐break, 60 mJ mm−3, was achieved for the film containing 30 wt% silica. All these materials can potentially be used as soft‐to‐hard topcoats, depending on the specific demands.

Název v anglickém jazyce

Novel waterborne poly(urethane‐urea)/silica nanocomposites

Popis výsledku anglicky

A series of novel transparent mechanically strong waterborne poly(urethane‐urea)/silica nanocomposites were prepared by mixing a waterborne poly(urethane‐urea) dispersion with aqueous nanosilica, followed by slow water evaporation. This procedure is simple, environmentally friendly and energetically undemanding. The silica content in the nanocomposite film varied from 0 to 50 wt%. Based on changes of tensile characteristics, for example, Young's modulus values, three types of behavior were observed: typical elastic (0‐10 wt%), plastic (30 wt%) and ceramic‐like (50 wt% silica) materials can be prepared. However, some films feature both elastic and plastic (material with 20 wt% silica) or plastic and ceramic‐like characteristics (material with 40 wt% silica). The Young's modulus varied from 6 to 705 MPa, and the maximal tensile strength and elongation‐at‐break were 17.3 MPa and 1270%, respectively. The maximum energy‐to‐break, 60 mJ mm−3, was achieved for the film containing 30 wt% silica. All these materials can potentially be used as soft‐to‐hard topcoats, depending on the specific demands.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

<a href="/cs/project/GA18-03932S" target="_blank" >GA18-03932S: Polyuretany s řízeně zabudovanými anorganickými/organickými bloky a regulovatelnou hydrolytickou stabilitou</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polymer Composites

ISSN

0272-8397

e-ISSN

—

Svazek periodika

41

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

12

Strana od-do

4031-4042

Kód UT WoS článku

000541178400001

EID výsledku v databázi Scopus

2-s2.0-85087209852