Conducting polypyrrole-coated leathers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F23%3A00570027" target="_blank" >RIV/61389013:_____/23:00570027 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/70883521:28610/23:63566758 RIV/60461373:22340/23:43927596 RIV/60461373:22810/23:43927596

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0300944023000917?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0300944023000917?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.porgcoat.2023.107495" target="_blank" >10.1016/j.porgcoat.2023.107495</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Conducting polypyrrole-coated leathers

Popis výsledku v původním jazyce

Conducting polymers are promising materials applicable as interfaces in various functional materials given they intrinsically possess electronic and ionic conductivity. Herein, a conducting polymer, polypyrrole (PPy) was explored for surface modification of three different leathers via in-situ oxidation of pyrrole in the absence and the presence of two stabilizing polymers, hydroxypropylcellulose and poly(N-vinylpyrrolidone). Colloidal dispersed PPy assemblies were formed with colloidal stabilizers along with PPy-coated leathers and hampered the formation of PPy precipitates that would otherwise contaminate the leather surface. The surface-modified bio-based composites were characterized by FTIR and Raman spectroscopy, and optical and scanning electron microscopy. PPy was deposited on collagen fibers on both sides of the leather. The thickness of the PPy layer varied between 24 and 200 μm. Mechanical properties of the leathers manifested themselves by the decrease in tensile strength and elongation at break after the modification process. Sheet resistances were in the range of 100–103 kΩ/sq with the highest values observed for materials modified in the presence of the polymeric stabilizers. Different sheet resistances were obtained for the top and bottom sides of the leathers depending on the surface finishing. Furthermore, the modified leathers were subjected to cyclic bending tests and the variation in their resistivity was studied. The conductivity and electroactivity of the modified materials may serve as guidance for the rational design of intelligent leathers in the footwear, as heating elements, and in energy storage.

Název v anglickém jazyce

Conducting polypyrrole-coated leathers

Popis výsledku anglicky

Conducting polymers are promising materials applicable as interfaces in various functional materials given they intrinsically possess electronic and ionic conductivity. Herein, a conducting polymer, polypyrrole (PPy) was explored for surface modification of three different leathers via in-situ oxidation of pyrrole in the absence and the presence of two stabilizing polymers, hydroxypropylcellulose and poly(N-vinylpyrrolidone). Colloidal dispersed PPy assemblies were formed with colloidal stabilizers along with PPy-coated leathers and hampered the formation of PPy precipitates that would otherwise contaminate the leather surface. The surface-modified bio-based composites were characterized by FTIR and Raman spectroscopy, and optical and scanning electron microscopy. PPy was deposited on collagen fibers on both sides of the leather. The thickness of the PPy layer varied between 24 and 200 μm. Mechanical properties of the leathers manifested themselves by the decrease in tensile strength and elongation at break after the modification process. Sheet resistances were in the range of 100–103 kΩ/sq with the highest values observed for materials modified in the presence of the polymeric stabilizers. Different sheet resistances were obtained for the top and bottom sides of the leathers depending on the surface finishing. Furthermore, the modified leathers were subjected to cyclic bending tests and the variation in their resistivity was studied. The conductivity and electroactivity of the modified materials may serve as guidance for the rational design of intelligent leathers in the footwear, as heating elements, and in energy storage.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Progress in Organic Coatings

ISSN

0300-9440

e-ISSN

1873-331X

Svazek periodika

179

Číslo periodika v rámci svazku

June

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

10

Strana od-do

107495

Kód UT WoS článku

000952522200001

EID výsledku v databázi Scopus

2-s2.0-85148997209