The implication of PMMA molecular weight on compatibility of SAN/PMMA blends containing GO-g-PMMA hybrid compatibilizers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F23%3A00577401" target="_blank" >RIV/61389013:_____/23:00577401 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/70883521:28110/23:63570079 RIV/70883521:28610/23:63570079

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2352492823020846?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352492823020846?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mtcomm.2023.107393" target="_blank" >10.1016/j.mtcomm.2023.107393</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The implication of PMMA molecular weight on compatibility of SAN/PMMA blends containing GO-g-PMMA hybrid compatibilizers

Popis výsledku v původním jazyce

The molecular weight of a polymer is one of the most important factors defining material properties and performance. Within the current study, poly(styrene-co-acrylonitrile)/poly(methyl methacrylate) (SAN/PMMA) blends containing hybrid particles of graphene oxide-g-poly(methyl methacrylate) (GO-g-PMMA) were designed so that the molecular weight of the PMMA chains tethered on the GO particles was correlated with the molecular weight of the PMMA matrix. Hybrid particles were prepared using surface-initiated atom transfer radical polymerization (ATRP). The number average molecular weight of the matrix PMMA was Mn = 20,100 or 130,900 g/mol, while in the case of hybrids it was Mn = 5600, 27,300 or 191,600 g/mol. Two blend compositions were investigated: SAN/PMMA= 70/30 and 90/10 wt/wt, and the content of GO-g-PMMA was 1 wt%. Based on rheological studies it was demonstrated that higher molecular weights of the matrix PMMA promoted the compatibility of SAN/PMMA due to the similar viscosity of both blend components. Furthermore, the length of the PMMA chains grafted to the GO influenced the viscoelastic response of the material, resulting in different relaxation behavior as confirmed by mean relaxation times calculated from Cole-Cole plots. In addition, the effect of neat GO and GO-g-PMMA particles on the blend morphology and size distribution of PMMA droplets was discussed based on rheology and TEM analyses.

Název v anglickém jazyce

The implication of PMMA molecular weight on compatibility of SAN/PMMA blends containing GO-g-PMMA hybrid compatibilizers

Popis výsledku anglicky

The molecular weight of a polymer is one of the most important factors defining material properties and performance. Within the current study, poly(styrene-co-acrylonitrile)/poly(methyl methacrylate) (SAN/PMMA) blends containing hybrid particles of graphene oxide-g-poly(methyl methacrylate) (GO-g-PMMA) were designed so that the molecular weight of the PMMA chains tethered on the GO particles was correlated with the molecular weight of the PMMA matrix. Hybrid particles were prepared using surface-initiated atom transfer radical polymerization (ATRP). The number average molecular weight of the matrix PMMA was Mn = 20,100 or 130,900 g/mol, while in the case of hybrids it was Mn = 5600, 27,300 or 191,600 g/mol. Two blend compositions were investigated: SAN/PMMA= 70/30 and 90/10 wt/wt, and the content of GO-g-PMMA was 1 wt%. Based on rheological studies it was demonstrated that higher molecular weights of the matrix PMMA promoted the compatibility of SAN/PMMA due to the similar viscosity of both blend components. Furthermore, the length of the PMMA chains grafted to the GO influenced the viscoelastic response of the material, resulting in different relaxation behavior as confirmed by mean relaxation times calculated from Cole-Cole plots. In addition, the effect of neat GO and GO-g-PMMA particles on the blend morphology and size distribution of PMMA droplets was discussed based on rheology and TEM analyses.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials Today Communications

ISSN

2352-4928

e-ISSN

2352-4928

Svazek periodika

37

Číslo periodika v rámci svazku

December

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

107393

Kód UT WoS článku

001104436900001

EID výsledku v databázi Scopus

2-s2.0-85174694524