Polymerization of renewable itaconic acid in deep eutectic monomers: effect of the quaternary ammonium cation structure

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F24%3A00580221" target="_blank" >RIV/61389013:_____/24:00580221 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0014305723008601?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0014305723008601?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.eurpolymj.2023.112677" target="_blank" >10.1016/j.eurpolymj.2023.112677</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Polymerization of renewable itaconic acid in deep eutectic monomers: effect of the quaternary ammonium cation structure

Popis výsledku v původním jazyce

A systematic investigation has been carried out on the synthesis of poly(itaconic acid) (PIA) in Deep Eutectic Monomer (DEM) systems, composed of bio-derived itaconic acid (IA) and quaternary ammonium chlorides (QCl) varying in their cation structure. The physicochemical properties including density, viscosity, Kamlet-Taft parameters and polarity as Nile Red transition energy of DEMs supported with spectroscopic studies (FT-IR, 1H and 13C NMR) are reported. It was observed that cation structure of the ammonium chloride impacts on the physicochemical properties and radical polymerization of DEMs. More notably, the correlations between the Kamlet-Taft hydrogen bonding accepting ability (β) of the DEMs and both IA polymerization rate and the molecular weight of the synthesized PIA were found. These findings provided theoretical guidance on designing DEMs tailored to specific polymerization process.

Název v anglickém jazyce

Polymerization of renewable itaconic acid in deep eutectic monomers: effect of the quaternary ammonium cation structure

Popis výsledku anglicky

A systematic investigation has been carried out on the synthesis of poly(itaconic acid) (PIA) in Deep Eutectic Monomer (DEM) systems, composed of bio-derived itaconic acid (IA) and quaternary ammonium chlorides (QCl) varying in their cation structure. The physicochemical properties including density, viscosity, Kamlet-Taft parameters and polarity as Nile Red transition energy of DEMs supported with spectroscopic studies (FT-IR, 1H and 13C NMR) are reported. It was observed that cation structure of the ammonium chloride impacts on the physicochemical properties and radical polymerization of DEMs. More notably, the correlations between the Kamlet-Taft hydrogen bonding accepting ability (β) of the DEMs and both IA polymerization rate and the molecular weight of the synthesized PIA were found. These findings provided theoretical guidance on designing DEMs tailored to specific polymerization process.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

<a href="/cs/project/GF21-07004K" target="_blank" >GF21-07004K: Polyelektrolyty na bázi kyseliny itakonové získané z biomasy pro syntézu samouspořádaných nanokompozitních hydrogelů</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Polymer Journal

ISSN

0014-3057

e-ISSN

1873-1945

Svazek periodika

203

Číslo periodika v rámci svazku

19 January

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

112677

Kód UT WoS článku

001145707000001

EID výsledku v databázi Scopus

2-s2.0-85180754100