Liquid plasma spraying of NiO-YSZ anode layers applicable for SOFC

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389021%3A_____%2F24%3A00584163" target="_blank" >RIV/61389021:_____/24:00584163 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68407700:21230/24:00373415 RIV/60461373:22310/24:43927594

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2352492823025461?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352492823025461?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mtcomm.2023.107855" target="_blank" >10.1016/j.mtcomm.2023.107855</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Liquid plasma spraying of NiO-YSZ anode layers applicable for SOFC

Popis výsledku v původním jazyce

Plasma spraying (PS) from liquid feedstocks is a promising alternative for fabricating the NiO-YSZ anodes for Solid Oxide Fuel Cell (SOFC). However, despite the inherent advantages of the PS process, the plasma sprayed anodes are still inferior to the conventional ones prepared by wet-ceramic techniques due to the difficulty of achieving the optimal porosity level. This study shows that due to recent development, the NiO-YSZ anode layers with desirable porosity and microstructure can now be effectively fabricated in a one-step process using PS equipment with a water-argon stabilized plasma torch. As a liquid feedstock, we utilized Ni nitrate (hexahydrate) solutions and YSZ suspensions with different ratios, using ethanol or water as solvents. We show that the ethanol-based feedstock provides a favorable microstructure and porosity of the resulted layers over the water-based one. In addition, apart from NiO and YSZ phases, the layers deposited with ethanol solvent contained even metallic Ni. Different ratios of Ni nitrate to YSZ in ethanol-based feedstocks greatly affected the layer's characteristics - when the content of Ni nitrate was high, the resulting layers had a non-uniform morphology with a very porous microstructure. On the contrary, the equal contents of Ni nitrate and YSZ in the feedstock resulted in the most optimal layer's microstructure, chemical composition, and thus sufficient electrical resistance, making such material potentially useful as anode for SOFC.

Název v anglickém jazyce

Liquid plasma spraying of NiO-YSZ anode layers applicable for SOFC

Popis výsledku anglicky

Plasma spraying (PS) from liquid feedstocks is a promising alternative for fabricating the NiO-YSZ anodes for Solid Oxide Fuel Cell (SOFC). However, despite the inherent advantages of the PS process, the plasma sprayed anodes are still inferior to the conventional ones prepared by wet-ceramic techniques due to the difficulty of achieving the optimal porosity level. This study shows that due to recent development, the NiO-YSZ anode layers with desirable porosity and microstructure can now be effectively fabricated in a one-step process using PS equipment with a water-argon stabilized plasma torch. As a liquid feedstock, we utilized Ni nitrate (hexahydrate) solutions and YSZ suspensions with different ratios, using ethanol or water as solvents. We show that the ethanol-based feedstock provides a favorable microstructure and porosity of the resulted layers over the water-based one. In addition, apart from NiO and YSZ phases, the layers deposited with ethanol solvent contained even metallic Ni. Different ratios of Ni nitrate to YSZ in ethanol-based feedstocks greatly affected the layer's characteristics - when the content of Ni nitrate was high, the resulting layers had a non-uniform morphology with a very porous microstructure. On the contrary, the equal contents of Ni nitrate and YSZ in the feedstock resulted in the most optimal layer's microstructure, chemical composition, and thus sufficient electrical resistance, making such material potentially useful as anode for SOFC.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

<a href="/cs/project/GA22-21478S" target="_blank" >GA22-21478S: Vysokoentalpická depozice hybridních plazmových nástřiků</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials Today Communications

ISSN

2352-4928

e-ISSN

2352-4928

Svazek periodika

38

Číslo periodika v rámci svazku

March

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

14

Strana od-do

107855

Kód UT WoS článku

001149072900001

EID výsledku v databázi Scopus

2-s2.0-85180936511