PEI-Schiff base-modified mesoporous silica materials SBA-12, 15 and 16 for toxic metal ions capture (Co(II), Ni(II) and Cu(II)): Effect of morphology, post-synthetic modification and kinetic study

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F23%3AA2402KW1" target="_blank" >RIV/61988987:17310/23:A2402KW1 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2352492823007407" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2352492823007407</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mtcomm.2023.106049" target="_blank" >10.1016/j.mtcomm.2023.106049</a>

Jazyk výsledku

angličtina

Název v původním jazyce

PEI-Schiff base-modified mesoporous silica materials SBA-12, 15 and 16 for toxic metal ions capture (Co(II), Ni(II) and Cu(II)): Effect of morphology, post-synthetic modification and kinetic study

Popis výsledku v původním jazyce

A series of SBA materials (SBA-12, SBA-15, and SBA-16) with polyethyleneimine (PEI) and its Schiff base variants with salicylaldehyde-modified samples (PS) have been successfully prepared and characterized. The synthesized materials were investigated by infrared spectroscopy (FT-IR), and quantification of the organic part coated on the surface was studied using thermogravimetric analysis (TGA). Nitrogen adsorption/desorption analysis at − 196 °C (N2), bright field scanning transmission electron microscopy (BF-STEM) and small angle X-ray scattering (SAXS) measurements were used to study textural properties, structure and morphology. Confirmation of heavy metal ions capture in pores of prepared materials was proved by X-ray fluorescence analysis (XRF), and nitrate anions were confirmed by FT-IR spectroscopy. Kinetic studies were performed by conductometric analysis (CA) and showed that the mathematical models could be applied to adsorption processes with a non-linear decreasing trend. This trend appeared in PS-modified SBA systems and some non-modified samples. The best overall adsorption properties were observed for material SBA-12 and its modified types. In this case, material SBA-12-PS can trap 54.38 mg g−1 of Cu(NO3)2 or 18.42 mg of Cu(II) ions, 112.84 mg g−1 of Ni(NO3)2 corresponding to 36.24 mg of Ni(II) cations, and 39.56 mg g−1 of Co(NO3)2 representing 12.74 mg of Co(II) ions. Non-modified materials show morphological effects where 2D ordered pores with hexagonal symmetry and the biggest mesopores (5.5 nm) have the best overall results in adsorption capacity of metal ions (Cu(II): 11.95 mg g−1) calculated from pseudo-second order.

Název v anglickém jazyce

PEI-Schiff base-modified mesoporous silica materials SBA-12, 15 and 16 for toxic metal ions capture (Co(II), Ni(II) and Cu(II)): Effect of morphology, post-synthetic modification and kinetic study

Popis výsledku anglicky

A series of SBA materials (SBA-12, SBA-15, and SBA-16) with polyethyleneimine (PEI) and its Schiff base variants with salicylaldehyde-modified samples (PS) have been successfully prepared and characterized. The synthesized materials were investigated by infrared spectroscopy (FT-IR), and quantification of the organic part coated on the surface was studied using thermogravimetric analysis (TGA). Nitrogen adsorption/desorption analysis at − 196 °C (N2), bright field scanning transmission electron microscopy (BF-STEM) and small angle X-ray scattering (SAXS) measurements were used to study textural properties, structure and morphology. Confirmation of heavy metal ions capture in pores of prepared materials was proved by X-ray fluorescence analysis (XRF), and nitrate anions were confirmed by FT-IR spectroscopy. Kinetic studies were performed by conductometric analysis (CA) and showed that the mathematical models could be applied to adsorption processes with a non-linear decreasing trend. This trend appeared in PS-modified SBA systems and some non-modified samples. The best overall adsorption properties were observed for material SBA-12 and its modified types. In this case, material SBA-12-PS can trap 54.38 mg g−1 of Cu(NO3)2 or 18.42 mg of Cu(II) ions, 112.84 mg g−1 of Ni(NO3)2 corresponding to 36.24 mg of Ni(II) cations, and 39.56 mg g−1 of Co(NO3)2 representing 12.74 mg of Co(II) ions. Non-modified materials show morphological effects where 2D ordered pores with hexagonal symmetry and the biggest mesopores (5.5 nm) have the best overall results in adsorption capacity of metal ions (Cu(II): 11.95 mg g−1) calculated from pseudo-second order.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

<a href="/cs/project/LUASK22049" target="_blank" >LUASK22049: Monolitické, hierarchicky porézní MOF-uhlíkaté kompozity pro environmentální aplikace</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials Today Communications

ISSN

23524928

e-ISSN

—

Svazek periodika

—

Číslo periodika v rámci svazku

06/2023

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

20

Strana od-do

—

Kód UT WoS článku

001009126000001

EID výsledku v databázi Scopus

2-s2.0-85153066907