Fabrication of a highly efficient CuO/ZnCo2O4/CNTs ternary composite for photocatalytic degradation of hazardous pollutants

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61988987%3A17310%2F24%3AA25038AZ" target="_blank" >RIV/61988987:17310/24:A25038AZ - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.rsc.org/en/content/articlelanding/2024/ra/d4ra04395b" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2024/ra/d4ra04395b</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d4ra04395b" target="_blank" >10.1039/d4ra04395b</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Fabrication of a highly efficient CuO/ZnCo2O4/CNTs ternary composite for photocatalytic degradation of hazardous pollutants

Popis výsledku v původním jazyce

In the current study, CuO, ZnCo2O4, CuO/ZnCo2O4, and CuO/ZnCo2O4/CNTs photocatalysts were prepared to remove crystal violet (CV) and colorless pollutants (diclofenac sodium and phenol) from wastewater. Herein, sol-gel and co-precipitation methods were used to synthesize CuO and ZnCo2O4, respectively. The sonication method was used to synthesize CuO/ZnCo2O4 and a CNTs-based composite (CuO/ZnCo2O4/CNTs). From the UV-Vis spectra of CuO, ZnCo2O4, CuO/ZnCo2O4, and CuO/ZnCo2O4/CNTs, the optical band gap value was calculated to be 2.11, 2.18, 1.71 and 1.63 eV respectively. The photocatalytic results revealed that CuO/ZnCo2O4/CNTs exhibited higher degradation of 87.7% against CV dye, 82% against diclofenac sodium, and 72% against phenol as compared to other prepared photocatalysts. The OH center dot radical is identified as the active species in the photocatalytic process over CuO/ZnCo2O4/CNTs. The impact of several parameters, such as pH, concentration, and catalyst dosage, has also been investigated. The better activity of the CNTs-based composite was due to the synergic effect of both CuO/ZnCo2O4 nanocomposite and carbon nanotubes. Therefore, the synthesized CuO/ZnCo2O4/CNTs photocatalyst has the potential to degrade organic wastewater effluents effectively.

Název v anglickém jazyce

Fabrication of a highly efficient CuO/ZnCo2O4/CNTs ternary composite for photocatalytic degradation of hazardous pollutants

Popis výsledku anglicky

In the current study, CuO, ZnCo2O4, CuO/ZnCo2O4, and CuO/ZnCo2O4/CNTs photocatalysts were prepared to remove crystal violet (CV) and colorless pollutants (diclofenac sodium and phenol) from wastewater. Herein, sol-gel and co-precipitation methods were used to synthesize CuO and ZnCo2O4, respectively. The sonication method was used to synthesize CuO/ZnCo2O4 and a CNTs-based composite (CuO/ZnCo2O4/CNTs). From the UV-Vis spectra of CuO, ZnCo2O4, CuO/ZnCo2O4, and CuO/ZnCo2O4/CNTs, the optical band gap value was calculated to be 2.11, 2.18, 1.71 and 1.63 eV respectively. The photocatalytic results revealed that CuO/ZnCo2O4/CNTs exhibited higher degradation of 87.7% against CV dye, 82% against diclofenac sodium, and 72% against phenol as compared to other prepared photocatalysts. The OH center dot radical is identified as the active species in the photocatalytic process over CuO/ZnCo2O4/CNTs. The impact of several parameters, such as pH, concentration, and catalyst dosage, has also been investigated. The better activity of the CNTs-based composite was due to the synergic effect of both CuO/ZnCo2O4 nanocomposite and carbon nanotubes. Therefore, the synthesized CuO/ZnCo2O4/CNTs photocatalyst has the potential to degrade organic wastewater effluents effectively.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

RSC Advances

ISSN

2046-2069

e-ISSN

2046-2069

Svazek periodika

—

Číslo periodika v rámci svazku

34

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

23

Strana od-do

24874-24897

Kód UT WoS článku

001286692900001

EID výsledku v databázi Scopus

2-s2.0-85201102990