Magnetic Sorbents Biomineralization on the Basis of Iron Sulphides

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27350%2F17%3A10237857" target="_blank" >RIV/61989100:27350/17:10237857 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989100:27640/17:10237857

Výsledek na webu

<a href="http://www.tandfonline.com/doi/abs/10.1080/09593330.2017.1369581?journalCode=tent20" target="_blank" >http://www.tandfonline.com/doi/abs/10.1080/09593330.2017.1369581?journalCode=tent20</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/09593330.2017.1369581" target="_blank" >10.1080/09593330.2017.1369581</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Magnetic Sorbents Biomineralization on the Basis of Iron Sulphides

Popis výsledku v původním jazyce

Biomineralization means mineral formation under the influence of organisms. Sulphate-reducing bacteria (SRB) constitute an essential role of iron sulphide minerals precipitation. Their composition involves amorphous, non-stoichiometric or crystalline iron sulphides, weakly or strongly magnetic. Variation in environmental conditions can alter the reactive iron species within the mineral, potentially modifying their magnetic properties. Biogenic iron sulphide minerals can be used as heavy metals and toxic ions adsorbents in soil or water remediation. For these reasons, a series of laboratory-scale iron sulphide synthesis experiments with the aim to study the chemical composition, mineralogy and magnetic properties of iron sulphide precipitates were carried out using SRB under various cultivation mode and nutrient medium composition. Energy-dispersive X-ray analysis (EDX) showed formation of iron sulphides in all biogenic samples and iron phosphates in abiotic controls. Results of X-ray diffraction analysis (XRD) in biomineralized samples confirmed nanocrystalline greigite, mackinawite and sulphur alpha. Magnetic measurements showed that sample prepared by static cultivation without addition of fresh nutrient medium was the most magnetic, magnetic hysteresis of sample formed under semicontinuous mode without any nutrient supply was the lowest. Abiotic samples contained only vivianite and they did not prove any significant response to magnetic field.

Název v anglickém jazyce

Magnetic Sorbents Biomineralization on the Basis of Iron Sulphides

Popis výsledku anglicky

Biomineralization means mineral formation under the influence of organisms. Sulphate-reducing bacteria (SRB) constitute an essential role of iron sulphide minerals precipitation. Their composition involves amorphous, non-stoichiometric or crystalline iron sulphides, weakly or strongly magnetic. Variation in environmental conditions can alter the reactive iron species within the mineral, potentially modifying their magnetic properties. Biogenic iron sulphide minerals can be used as heavy metals and toxic ions adsorbents in soil or water remediation. For these reasons, a series of laboratory-scale iron sulphide synthesis experiments with the aim to study the chemical composition, mineralogy and magnetic properties of iron sulphide precipitates were carried out using SRB under various cultivation mode and nutrient medium composition. Energy-dispersive X-ray analysis (EDX) showed formation of iron sulphides in all biogenic samples and iron phosphates in abiotic controls. Results of X-ray diffraction analysis (XRD) in biomineralized samples confirmed nanocrystalline greigite, mackinawite and sulphur alpha. Magnetic measurements showed that sample prepared by static cultivation without addition of fresh nutrient medium was the most magnetic, magnetic hysteresis of sample formed under semicontinuous mode without any nutrient supply was the lowest. Abiotic samples contained only vivianite and they did not prove any significant response to magnetic field.

Druh

J_ost - Ostatní články v recenzovaných periodicích

CEP obor

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OECD FORD obor

10303 - Particles and field physics

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Environmental Technology

ISSN

0959-3330

e-ISSN

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Svazek periodika

neuveden

Číslo periodika v rámci svazku

neuveden

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

1-10

Kód UT WoS článku

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EID výsledku v databázi Scopus

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