Development of Porous Coatings Enriched with Magnesium and Zinc Obtained by DC Plasma Electrolytic Oxidation

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27350%2F18%3A10239156" target="_blank" >RIV/61989100:27350/18:10239156 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.mdpi.com/2072-666X/9/7/332" target="_blank" >https://www.mdpi.com/2072-666X/9/7/332</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/mi9070332" target="_blank" >10.3390/mi9070332</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Development of Porous Coatings Enriched with Magnesium and Zinc Obtained by DC Plasma Electrolytic Oxidation

Popis výsledku v původním jazyce

Coatings with developed surface stereometry, being based on a porous system, may be obtained by plasma electrolytic oxidation, PEO (micro arc oxidation, MAO). In this paper, we present novel porous coatings, which may be used, e.g., in micromachine&apos;s biocompatible sensors&apos; housing, obtained in electrolytes containing magnesium nitrate hexahydrate Mg(NO3)(2)center dot 6H(2)O and/or zinc nitrate hexahydrate Zn(NO3)(2)center dot 6H(2)O in concentrated phosphoric acid H3PO4 (85% w/w). Complementary techniques are used for coatings&apos; surface characterization, such as scanning electron microscopy (SEM), for surface imaging as well as for chemical semi-quantitative analysis via energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), glow discharge optical emission spectroscopy (GDOES), and X-ray powder diffraction (XRD). The results have shown that increasing contents of salts (here, 250 g/L Mg(NO3)(2)center dot 6H(2)O and 250 g/L Zn(NO3)(2)center dot 6H(2)O) in electrolyte result in increasing of Mg/P and Zn/P ratios, as well as coating thickness. It was also found that by increasing the PEO voltage, the Zn/P and Mg/P ratios increase as well. In addition, the analysis of XPS spectra revealed the existence in 10 nm top of coating magnesium (Mg2+), zinc (Zn2+), titanium (Ti4+), and phosphorus compounds (PO43-, or HPO42-, or H2PO4-, or P2O74-).

Název v anglickém jazyce

Development of Porous Coatings Enriched with Magnesium and Zinc Obtained by DC Plasma Electrolytic Oxidation

Popis výsledku anglicky

Coatings with developed surface stereometry, being based on a porous system, may be obtained by plasma electrolytic oxidation, PEO (micro arc oxidation, MAO). In this paper, we present novel porous coatings, which may be used, e.g., in micromachine&apos;s biocompatible sensors&apos; housing, obtained in electrolytes containing magnesium nitrate hexahydrate Mg(NO3)(2)center dot 6H(2)O and/or zinc nitrate hexahydrate Zn(NO3)(2)center dot 6H(2)O in concentrated phosphoric acid H3PO4 (85% w/w). Complementary techniques are used for coatings&apos; surface characterization, such as scanning electron microscopy (SEM), for surface imaging as well as for chemical semi-quantitative analysis via energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), glow discharge optical emission spectroscopy (GDOES), and X-ray powder diffraction (XRD). The results have shown that increasing contents of salts (here, 250 g/L Mg(NO3)(2)center dot 6H(2)O and 250 g/L Zn(NO3)(2)center dot 6H(2)O) in electrolyte result in increasing of Mg/P and Zn/P ratios, as well as coating thickness. It was also found that by increasing the PEO voltage, the Zn/P and Mg/P ratios increase as well. In addition, the analysis of XPS spectra revealed the existence in 10 nm top of coating magnesium (Mg2+), zinc (Zn2+), titanium (Ti4+), and phosphorus compounds (PO43-, or HPO42-, or H2PO4-, or P2O74-).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Micromachines

ISSN

2072-666X

e-ISSN

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Svazek periodika

9

Číslo periodika v rámci svazku

7

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

19

Strana od-do

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Kód UT WoS článku

000441156000020

EID výsledku v databázi Scopus

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