Photocatalytic Decomposition of N2O Over Ceramics Cordierite/CeO2 Nanoparticles

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F19%3A10242505" target="_blank" >RIV/61989100:27360/19:10242505 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989100:27710/19:10242505

Výsledek na webu

<a href="https://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=1&SID=D2R1dw54um4kUfqLkoO&page=1&doc=1" target="_blank" >https://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=1&SID=D2R1dw54um4kUfqLkoO&page=1&doc=1</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1166/jnn.2019.15840" target="_blank" >10.1166/jnn.2019.15840</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Photocatalytic Decomposition of N2O Over Ceramics Cordierite/CeO2 Nanoparticles

Popis výsledku v původním jazyce

The study is focused on the testing of the photocatalytic ability to decompose nitrous oxide (N2O) over cordierite/CeO2 nanoparticles ceramic photocatalysts. The activity of ceramic materials was compared with the activity of industrially produced TiO2 (Evonik photocatalyst). Photocatalytic decomposition of N2O over the ceramic samples and the TiO2 Evonik was performed in annular batch reactor illuminated with 8 W Hg lamp (lambda = 254 nm wavelength). Reaction kinetics was well described by pseudo 1st rate law. Photocatalytic activity of cordierite/CeO2 was better in comparison with TiO2 Evonik P25. The highest N2O conversion (56%) after 20 h of irradiation in inert gas was achieved over the sample with higher amount of CeO2. This photocatalyst sample was examined for photocatalytic activity in the decomposition of N2O in the three various gaseous feed mixtures. The gaseous feed mixtures were: N2O enriched with O-2 (6.5 mol.%); N2O enriched with H2O(25 mol.%) and N2O enriched with mixture of O-2 and H2O(6.5 mol.% and 25 mol.%, respectively). It is assumed that the reduced conversion of N2O (47%) observed in the flow of the mixture of N2O and H(2)Ocould be affected by the sorption of water vapor on/onto the photocatalyst &quot;active sites&quot; causing less penetration of light and thus reducing the efficiency of photocatalytic decomposition of N2O. The presence of oxygen in the N2O mixture had only little effect to photocatalytic decomposition of N2O.

Název v anglickém jazyce

Photocatalytic Decomposition of N2O Over Ceramics Cordierite/CeO2 Nanoparticles

Popis výsledku anglicky

The study is focused on the testing of the photocatalytic ability to decompose nitrous oxide (N2O) over cordierite/CeO2 nanoparticles ceramic photocatalysts. The activity of ceramic materials was compared with the activity of industrially produced TiO2 (Evonik photocatalyst). Photocatalytic decomposition of N2O over the ceramic samples and the TiO2 Evonik was performed in annular batch reactor illuminated with 8 W Hg lamp (lambda = 254 nm wavelength). Reaction kinetics was well described by pseudo 1st rate law. Photocatalytic activity of cordierite/CeO2 was better in comparison with TiO2 Evonik P25. The highest N2O conversion (56%) after 20 h of irradiation in inert gas was achieved over the sample with higher amount of CeO2. This photocatalyst sample was examined for photocatalytic activity in the decomposition of N2O in the three various gaseous feed mixtures. The gaseous feed mixtures were: N2O enriched with O-2 (6.5 mol.%); N2O enriched with H2O(25 mol.%) and N2O enriched with mixture of O-2 and H2O(6.5 mol.% and 25 mol.%, respectively). It is assumed that the reduced conversion of N2O (47%) observed in the flow of the mixture of N2O and H(2)Ocould be affected by the sorption of water vapor on/onto the photocatalyst &quot;active sites&quot; causing less penetration of light and thus reducing the efficiency of photocatalytic decomposition of N2O. The presence of oxygen in the N2O mixture had only little effect to photocatalytic decomposition of N2O.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of nanoscience and nanotechnology

ISSN

1533-4880

e-ISSN

—

Svazek periodika

19

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

6

Strana od-do

7339-7344

Kód UT WoS článku

000475752300058

EID výsledku v databázi Scopus

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