Processing of Metal Waste-Sludge from the Galvanizing Plants

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F22%3A10251077" target="_blank" >RIV/61989100:27360/22:10251077 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/04130081:_____/22:N0000033

Výsledek na webu

<a href="https://www.mdpi.com/2075-4701/12/11/1947" target="_blank" >https://www.mdpi.com/2075-4701/12/11/1947</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/met12111947" target="_blank" >10.3390/met12111947</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Processing of Metal Waste-Sludge from the Galvanizing Plants

Popis výsledku v původním jazyce

This paper deals with the possibility of obtaining zinc from waste galvanic sludge, which is formed during galvanic plating. The aim of the experimental and practical part was to obtain zinc after the leaching of galvanic sludge. Leaching was performed in sulfuric acid, nitric acid and hydrochloric acid at different temperatures and time intervals with the addition of oxidizing agents as hydrogen peroxide or ozone. A separation of the leach and filtrate using filtration followed. The leach was further processed by a precipitation of iron and other metals using various agents. After a further filtration, the electrolysis was performed in order to obtain pure zinc on the cathode at the electrical voltage of approximately 3.5 V. Leaching using a solution of sodium hydroxide or potassium hydroxide was also performed when the prior dissolving of a major part of zinc into the leach occurred, while iron and non-ferrous metals remained in the leaching residue. After the filtration of the leach, the electrolysis with a high zinc yield of a purity of more than 99% followed. This way seems to be an optimal one for building a semi-industrial line for galvanic sludge recycling. All the partial products, i.e., the leach, the leaching residue, the filtrate, the solid precipitate and the separated metal on the cathode were subjected to chemical analyses. The analyses results are presented in tables and graphs.

Název v anglickém jazyce

Processing of Metal Waste-Sludge from the Galvanizing Plants

Popis výsledku anglicky

This paper deals with the possibility of obtaining zinc from waste galvanic sludge, which is formed during galvanic plating. The aim of the experimental and practical part was to obtain zinc after the leaching of galvanic sludge. Leaching was performed in sulfuric acid, nitric acid and hydrochloric acid at different temperatures and time intervals with the addition of oxidizing agents as hydrogen peroxide or ozone. A separation of the leach and filtrate using filtration followed. The leach was further processed by a precipitation of iron and other metals using various agents. After a further filtration, the electrolysis was performed in order to obtain pure zinc on the cathode at the electrical voltage of approximately 3.5 V. Leaching using a solution of sodium hydroxide or potassium hydroxide was also performed when the prior dissolving of a major part of zinc into the leach occurred, while iron and non-ferrous metals remained in the leaching residue. After the filtration of the leach, the electrolysis with a high zinc yield of a purity of more than 99% followed. This way seems to be an optimal one for building a semi-industrial line for galvanic sludge recycling. All the partial products, i.e., the leach, the leaching residue, the filtrate, the solid precipitate and the separated metal on the cathode were subjected to chemical analyses. The analyses results are presented in tables and graphs.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

20501 - Materials engineering

Projekt

<a href="/cs/project/SS01020312" target="_blank" >SS01020312: Inovativní technologie uzavřeného cyklu cirkulace vody v procesu galvanického pokovování a zpracování kovonosných odpadů - kalů a filtračních koláčů z provozu galvanovny</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Metals

ISSN

2075-4701

e-ISSN

2075-4701

Svazek periodika

12

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

27

Strana od-do

nestrankovano

Kód UT WoS článku

000895724000001

EID výsledku v databázi Scopus

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