A Cobalt Nanocatalyst for the Hydrogenation and Oxidative Dehydrogenation of N-heterocycles
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F23%3A10253958" target="_blank" >RIV/61989100:27640/23:10253958 - isvavai.cz</a>
Výsledek na webu
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202301027" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202301027</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cctc.202301027" target="_blank" >10.1002/cctc.202301027</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
A Cobalt Nanocatalyst for the Hydrogenation and Oxidative Dehydrogenation of N-heterocycles
Popis výsledku v původním jazyce
Catalytic hydrogenation and oxidative dehydrogenation of N-heterocycles to produce tetrahydroquinoline and quinoline derivatives are important reactions of particular importance in the agrochemical and pharmaceutical industries. Herein, we report earth-abundant cobalt nanoparticles supported on hydroxyapatite (HAP) as an inexpensive and efficient catalyst for the hydrogenation and reverse oxidative dehydrogenation of N-heterocycles. The optimal nanocatalyst exhibits excellent activity in both reactions for a wide range of substrates including (iso)quinolines, acridine, benzo[h]quinoline, quinoxaline and indole. Reactions proceed under relatively mild conditions without requiring any additives. Non-noble catalyst for hydrogenation and oxidative dehydrogenation of N-heterocycles process: Pyrolysis of Co-PZ-TPA supported on hydroxyapatite resulting in an active and reusable core-shell nanocatalyst with high activity in hydrogenation and its reversible oxidative dehydrogenation of N-heterocycles.image
Název v anglickém jazyce
A Cobalt Nanocatalyst for the Hydrogenation and Oxidative Dehydrogenation of N-heterocycles
Popis výsledku anglicky
Catalytic hydrogenation and oxidative dehydrogenation of N-heterocycles to produce tetrahydroquinoline and quinoline derivatives are important reactions of particular importance in the agrochemical and pharmaceutical industries. Herein, we report earth-abundant cobalt nanoparticles supported on hydroxyapatite (HAP) as an inexpensive and efficient catalyst for the hydrogenation and reverse oxidative dehydrogenation of N-heterocycles. The optimal nanocatalyst exhibits excellent activity in both reactions for a wide range of substrates including (iso)quinolines, acridine, benzo[h]quinoline, quinoxaline and indole. Reactions proceed under relatively mild conditions without requiring any additives. Non-noble catalyst for hydrogenation and oxidative dehydrogenation of N-heterocycles process: Pyrolysis of Co-PZ-TPA supported on hydroxyapatite resulting in an active and reusable core-shell nanocatalyst with high activity in hydrogenation and its reversible oxidative dehydrogenation of N-heterocycles.image
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10400 - Chemical sciences
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2023
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
ChemCatChem
ISSN
1867-3880
e-ISSN
1867-3899
Svazek periodika
16
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
DE - Spolková republika Německo
Počet stran výsledku
9
Strana od-do
—
Kód UT WoS článku
001096392100001
EID výsledku v databázi Scopus
2-s2.0-85175633238