Metastable Ni(I)-TiO2-x Photocatalysts: Self-Amplifying H2 Evolution from Plain Water without Noble Metal Co-Catalyst and Sacrificial Agent
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27640%2F23%3A10253967" target="_blank" >RIV/61989100:27640/23:10253967 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/61989592:15640/23:73621669
Výsledek na webu
<a href="https://pubs.acs.org/doi/10.1021/jacs.3c08199" target="_blank" >https://pubs.acs.org/doi/10.1021/jacs.3c08199</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jacs.3c08199" target="_blank" >10.1021/jacs.3c08199</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Metastable Ni(I)-TiO2-x Photocatalysts: Self-Amplifying H2 Evolution from Plain Water without Noble Metal Co-Catalyst and Sacrificial Agent
Popis výsledku v původním jazyce
Decoration of semiconductor photocatalysts with cocatalysts is generally done by a step-by-step assembly process. Here, we describe the self-assembling and self-activating nature of a photocatalytic system that forms under illumination of reduced anatase TiO2 nanoparticles in an aqueous Ni2+ solution. UV illumination creates in situ a Ni+/TiO2/Ti3+ photocatalyst that self-activates and, over time, produces H2 at a higher rate. In situ X-ray absorption spectroscopy and electron paramagnetic resonance spectroscopy show that key to self-assembly and self-activation is the light-induced formation of defects in the semiconductor, which enables the formation of monovalent nickel (Ni+) surface states. Metallic nickel states, i.e., Ni0, do not form under the dark (resting state) or under illumination (active state). Once the catalyst is assembled, the Ni+ surface states act as electron relay for electron transfer to form H2 from water, in the absence of sacrificial species or noble metal cocatalysts. (C) 2023 The Authors. Published by American Chemical Society
Název v anglickém jazyce
Metastable Ni(I)-TiO2-x Photocatalysts: Self-Amplifying H2 Evolution from Plain Water without Noble Metal Co-Catalyst and Sacrificial Agent
Popis výsledku anglicky
Decoration of semiconductor photocatalysts with cocatalysts is generally done by a step-by-step assembly process. Here, we describe the self-assembling and self-activating nature of a photocatalytic system that forms under illumination of reduced anatase TiO2 nanoparticles in an aqueous Ni2+ solution. UV illumination creates in situ a Ni+/TiO2/Ti3+ photocatalyst that self-activates and, over time, produces H2 at a higher rate. In situ X-ray absorption spectroscopy and electron paramagnetic resonance spectroscopy show that key to self-assembly and self-activation is the light-induced formation of defects in the semiconductor, which enables the formation of monovalent nickel (Ni+) surface states. Metallic nickel states, i.e., Ni0, do not form under the dark (resting state) or under illumination (active state). Once the catalyst is assembled, the Ni+ surface states act as electron relay for electron transfer to form H2 from water, in the absence of sacrificial species or noble metal cocatalysts. (C) 2023 The Authors. Published by American Chemical Society
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
21000 - Nano-technology
Návaznosti výsledku
Projekt
<a href="/cs/project/EF15_003%2F0000416" target="_blank" >EF15_003/0000416: Pokročilé hybridní nanostruktury pro aplikaci v obnovitelných zdrojích energie</a><br>
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2023
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
1520-5126
Svazek periodika
145
Číslo periodika v rámci svazku
48
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
11
Strana od-do
26122-26132
Kód UT WoS článku
001123090300001
EID výsledku v databázi Scopus
2-s2.0-85178569996