Experimental and theoretical studies of sonically prepared cu-y, cu-usy and cu-zsm-5 catalysts for scr denox

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27710%2F21%3A10248133" target="_blank" >RIV/61989100:27710/21:10248133 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11310/21:10438550

Výsledek na webu

<a href="http://file:///C:/Users/cha104/Downloads/catalysts-11-00824-v2.pdf" target="_blank" >http://file:///C:/Users/cha104/Downloads/catalysts-11-00824-v2.pdf</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal11070824" target="_blank" >10.3390/catal11070824</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Experimental and theoretical studies of sonically prepared cu-y, cu-usy and cu-zsm-5 catalysts for scr denox

Popis výsledku v původním jazyce

The objective of our study was to prepare Y-, USY-and ZSM-5-based catalysts by hydrothermal synthesis, followed by copper active-phase deposition by either conventional ion-exchange or ultrasonic irradiation. The resulting materials were characterized by XRD, BET, SEM, TEM, Ra-man, UV-Vis, monitoring ammonia and nitrogen oxide sorption by FT-IR and Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS). XRD data confirmed the purity and structure of the Y/USY or ZSM-5 zeolites. The nitrogen and ammonia sorption results indicated that the materials were highly porous and acidic. The metallic active phase was found in the form of cations in ion-exchanged zeolites and in the form of nanoparticle metal oxides in sonochemically prepared catalysts. The latter showed full activity and high stability in the SCR deNOx reaction. The faujasite-based catalysts were fully active at 200-400o C, whereas the ZSM-5-based catalysts reached 100% activity at 400-500o C. Our in situ DRIFTS experiments revealed that Cu-O(NO) and Cu-NH3 were intermediates, also indicating the role of Bronsted sites in the formation of NH4 NO3 . Furthermore, the results from our experimental in situ spectroscopic studies were compared with DFT models. Overall, our findings suggest two possible mechanisms for the deNOx reaction, depending on the method of catalyst preparation (i.e., conventional ion-exchange vs. ultrasonic irradiation).

Název v anglickém jazyce

Experimental and theoretical studies of sonically prepared cu-y, cu-usy and cu-zsm-5 catalysts for scr denox

Popis výsledku anglicky

The objective of our study was to prepare Y-, USY-and ZSM-5-based catalysts by hydrothermal synthesis, followed by copper active-phase deposition by either conventional ion-exchange or ultrasonic irradiation. The resulting materials were characterized by XRD, BET, SEM, TEM, Ra-man, UV-Vis, monitoring ammonia and nitrogen oxide sorption by FT-IR and Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS). XRD data confirmed the purity and structure of the Y/USY or ZSM-5 zeolites. The nitrogen and ammonia sorption results indicated that the materials were highly porous and acidic. The metallic active phase was found in the form of cations in ion-exchanged zeolites and in the form of nanoparticle metal oxides in sonochemically prepared catalysts. The latter showed full activity and high stability in the SCR deNOx reaction. The faujasite-based catalysts were fully active at 200-400o C, whereas the ZSM-5-based catalysts reached 100% activity at 400-500o C. Our in situ DRIFTS experiments revealed that Cu-O(NO) and Cu-NH3 were intermediates, also indicating the role of Bronsted sites in the formation of NH4 NO3 . Furthermore, the results from our experimental in situ spectroscopic studies were compared with DFT models. Overall, our findings suggest two possible mechanisms for the deNOx reaction, depending on the method of catalyst preparation (i.e., conventional ion-exchange vs. ultrasonic irradiation).

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

<a href="/cs/project/EF15_003%2F0000417" target="_blank" >EF15_003/0000417: Centrum pro cílenou syntézu a aplikace perspektivních materiálů</a><br>

Návaznosti

V - Vyzkumna aktivita podporovana z jinych verejnych zdroju

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

2073-4344

Svazek periodika

11

Číslo periodika v rámci svazku

7

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

21

Strana od-do

nestrankovano

Kód UT WoS článku

000676626000001

EID výsledku v databázi Scopus

2-s2.0-85109108501