Role of the Cu content and Ce activating effect on catalytic performance of Cu-Mg-Al and Ce/Cu-Mg-Al oxides in ammonia selective catalytic oxidation

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27710%2F22%3A10248130" target="_blank" >RIV/61989100:27710/22:10248130 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989100:27360/22:10248130

Výsledek na webu

<a href="https://www.webofscience.com/wos/woscc/full-record/WOS:000728392000004" target="_blank" >https://www.webofscience.com/wos/woscc/full-record/WOS:000728392000004</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.apsusc.2021.151540" target="_blank" >10.1016/j.apsusc.2021.151540</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Role of the Cu content and Ce activating effect on catalytic performance of Cu-Mg-Al and Ce/Cu-Mg-Al oxides in ammonia selective catalytic oxidation

Popis výsledku v původním jazyce

Copper-containing mixed metal oxides were studied as catalysts for selective catalytic oxidation of ammonia. The performed research shows a high correlation between Cu amount and catalyst efficiency, especially dinitrogen selectivity. Copper species, mainly in the form of highly dispersed CuO oxides, were found to be responsible for high N2 selectivity, which decreased with increasing Cu loading and the formation of CuO bulk-like species. The addition of cerium seemed to have an effect on material&apos;s catalytic activity and N2 selectivity. The increase in selectivity towards N2 of Ce-impregnated materials was attributed to the formation of copper-cerium redox couples on the material&apos;s surface. The catalytic tests performed under different NH3/O2 molar ratios revealed that the developed materials exhibit high catalytic activity in a wide range of ammonia concentrations and oxygen contents. (C) 2021 Elsevier B.V.

Název v anglickém jazyce

Role of the Cu content and Ce activating effect on catalytic performance of Cu-Mg-Al and Ce/Cu-Mg-Al oxides in ammonia selective catalytic oxidation

Popis výsledku anglicky

Copper-containing mixed metal oxides were studied as catalysts for selective catalytic oxidation of ammonia. The performed research shows a high correlation between Cu amount and catalyst efficiency, especially dinitrogen selectivity. Copper species, mainly in the form of highly dispersed CuO oxides, were found to be responsible for high N2 selectivity, which decreased with increasing Cu loading and the formation of CuO bulk-like species. The addition of cerium seemed to have an effect on material&apos;s catalytic activity and N2 selectivity. The increase in selectivity towards N2 of Ce-impregnated materials was attributed to the formation of copper-cerium redox couples on the material&apos;s surface. The catalytic tests performed under different NH3/O2 molar ratios revealed that the developed materials exhibit high catalytic activity in a wide range of ammonia concentrations and oxygen contents. (C) 2021 Elsevier B.V.

Druh

J_ost - Ostatní články v recenzovaných periodicích

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/EF17_049%2F0008419" target="_blank" >EF17_049/0008419: Podpora mezisektorové spolupráce v oblasti snižování polutantů v životním prostředí a využití odpadů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Applied Surface Science

ISSN

0169-4332

e-ISSN

—

Svazek periodika

573

Číslo periodika v rámci svazku

573 (2022) 151540

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

15

Strana od-do

—

Kód UT WoS článku

—

EID výsledku v databázi Scopus

2-s2.0-85117409812