Chemical recycling of waste polystyrene by thermo-catalytic pyrolysis: A description for different feedstocks, catalysts and operation modes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27710%2F22%3A10250007" target="_blank" >RIV/61989100:27710/22:10250007 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S014139102200163X" target="_blank" >https://www.sciencedirect.com/science/article/pii/S014139102200163X</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.polymdegradstab.2022.109981" target="_blank" >10.1016/j.polymdegradstab.2022.109981</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Chemical recycling of waste polystyrene by thermo-catalytic pyrolysis: A description for different feedstocks, catalysts and operation modes

Popis výsledku v původním jazyce

Chemical recycling by thermo-catalytic pyrolysis/degradation offers the possibility of converting waste plastics into their original monomers or other valuable chemicals which can be used as feedstocks in chemical and petrochemical industries. Plastic wastes of polystyrene (PS) based materials can be a good source of styrene as well as mono-aromatic (BTEX: benzene, toluene, ethylbenzene, xylenes) compounds. The selectivity of pyrolysis products can be tuned by choosing the right catalyst as well as appropriate operating conditions/operation modes. In this regard, the focus of the present work was to perform thermo-catalytic pyrolysis of different waste polystyrene (WPS) feedstocks over acid and base catalysts employed in ex-situ and in-situ modes. The main goal was to compare the compositions of pyrolysis products obtained by changing feedstocks, catalysts and operation modes. A further goal was to discuss the suitability of the catalysts employed for the enhanced recovery of desired products from WPS pyrolysis. It was demonstrated that expanded polystyrene gives very similar product distribution as compared to virgin PS, both giving high styrene content. Likewise, hard PS-based random packing materials produce similar results as compared to high impact polystyrene (HIPS). Moreover, it was shown that solid base catalysts influence the composition of the pyrolysis products only slightly as compared to thermolysis. Solid acid catalyst however, showed significant impact on the composition of the pyrolysis products as compared to non-catalytic pyrolysis. These results may provide new insights for the chemical recycling of plastic wastes. (C) 2022 Elsevier Ltd. All rights reserved.

Název v anglickém jazyce

Chemical recycling of waste polystyrene by thermo-catalytic pyrolysis: A description for different feedstocks, catalysts and operation modes

Popis výsledku anglicky

Chemical recycling by thermo-catalytic pyrolysis/degradation offers the possibility of converting waste plastics into their original monomers or other valuable chemicals which can be used as feedstocks in chemical and petrochemical industries. Plastic wastes of polystyrene (PS) based materials can be a good source of styrene as well as mono-aromatic (BTEX: benzene, toluene, ethylbenzene, xylenes) compounds. The selectivity of pyrolysis products can be tuned by choosing the right catalyst as well as appropriate operating conditions/operation modes. In this regard, the focus of the present work was to perform thermo-catalytic pyrolysis of different waste polystyrene (WPS) feedstocks over acid and base catalysts employed in ex-situ and in-situ modes. The main goal was to compare the compositions of pyrolysis products obtained by changing feedstocks, catalysts and operation modes. A further goal was to discuss the suitability of the catalysts employed for the enhanced recovery of desired products from WPS pyrolysis. It was demonstrated that expanded polystyrene gives very similar product distribution as compared to virgin PS, both giving high styrene content. Likewise, hard PS-based random packing materials produce similar results as compared to high impact polystyrene (HIPS). Moreover, it was shown that solid base catalysts influence the composition of the pyrolysis products only slightly as compared to thermolysis. Solid acid catalyst however, showed significant impact on the composition of the pyrolysis products as compared to non-catalytic pyrolysis. These results may provide new insights for the chemical recycling of plastic wastes. (C) 2022 Elsevier Ltd. All rights reserved.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20400 - Chemical engineering

Projekt

<a href="/cs/project/EF16_019%2F0000853" target="_blank" >EF16_019/0000853: Institut environmentálních technologií - excelentní výzkum</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polymer Degradation and Stability

ISSN

0141-3910

e-ISSN

1873-2321

Svazek periodika

201

Číslo periodika v rámci svazku

July 2022

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

nestrankovano

Kód UT WoS článku

000808400500007

EID výsledku v databázi Scopus

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