Pyrolysis of the anaerobic digestion solid by-product: Characterization of digestate decomposition and screening of the biochar use as soil amendment and as additive in anaerobic digestion

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27710%2F23%3A10251309" target="_blank" >RIV/61989100:27710/23:10251309 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.webofscience.com/wos/woscc/full-record/WOS:000925133700001" target="_blank" >https://www.webofscience.com/wos/woscc/full-record/WOS:000925133700001</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.enconman.2023.116658" target="_blank" >10.1016/j.enconman.2023.116658</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Pyrolysis of the anaerobic digestion solid by-product: Characterization of digestate decomposition and screening of the biochar use as soil amendment and as additive in anaerobic digestion

Popis výsledku v původním jazyce

An industrial digestate was tested under pyrolysis to validate the influence of various temperatures on the potential of waste to provide biochars capable to improve soil productivity and enhance the efficiency of anaerobic digestion. The thermochemical conversion of digestate and the related kinetics were also examined by thermogravimetry and compared to those of biomass. Digestate provided greater proportions of biochar (41.3-66.5 %wt.) than biomass (15.5-48.6 %wt.) at all temperatures, although cellulose and hemicellulose were less thermally stable than in the untreated biomass as indicated by the low activation energies of 150-180 kJ/mol and 83.1-88.2 kJ/mol, respectively compared to those of the polysaccharides in biomass. The behaviour of digestate during conversion and the quantity of generated biochar were both unaffected by the heating rate. Biochar yields however decreased from 55 to 41.3 %wt. in the isothermal tests with the increment of pyrolysis temperature from 300 to 700 oC. The soil amelioration ability of digestate was almost unaffected by pyrolysis at temperatures below 400 oC. Biochar produced at 500 oC possessed the greatest potential to improve soil fertility in the long-term due to its high alkalinity (pH 11.46) and modest cation exchange capacity (CEC) (72.2 cmol kgMINUS SIGN 1). The high-temperature biochar with slightly higher pH (11.51) and significantly larger surface area (116.1 m2/g) was the optimal choice for soil amelioration. Compared to the other biochars, the one produced at the highest temperature was also the best anaerobic digestion agent because of the higher alkalinity (pH 11.51), better minerals content (P, K, Ca, Al) and larger than 100 m2/g surface area, all properties that are desirable for the improvement of stability, methane productivity and mitigation of CO2, H2S and free-NH3 in a digestion system.

Název v anglickém jazyce

Pyrolysis of the anaerobic digestion solid by-product: Characterization of digestate decomposition and screening of the biochar use as soil amendment and as additive in anaerobic digestion

Popis výsledku anglicky

An industrial digestate was tested under pyrolysis to validate the influence of various temperatures on the potential of waste to provide biochars capable to improve soil productivity and enhance the efficiency of anaerobic digestion. The thermochemical conversion of digestate and the related kinetics were also examined by thermogravimetry and compared to those of biomass. Digestate provided greater proportions of biochar (41.3-66.5 %wt.) than biomass (15.5-48.6 %wt.) at all temperatures, although cellulose and hemicellulose were less thermally stable than in the untreated biomass as indicated by the low activation energies of 150-180 kJ/mol and 83.1-88.2 kJ/mol, respectively compared to those of the polysaccharides in biomass. The behaviour of digestate during conversion and the quantity of generated biochar were both unaffected by the heating rate. Biochar yields however decreased from 55 to 41.3 %wt. in the isothermal tests with the increment of pyrolysis temperature from 300 to 700 oC. The soil amelioration ability of digestate was almost unaffected by pyrolysis at temperatures below 400 oC. Biochar produced at 500 oC possessed the greatest potential to improve soil fertility in the long-term due to its high alkalinity (pH 11.46) and modest cation exchange capacity (CEC) (72.2 cmol kgMINUS SIGN 1). The high-temperature biochar with slightly higher pH (11.51) and significantly larger surface area (116.1 m2/g) was the optimal choice for soil amelioration. Compared to the other biochars, the one produced at the highest temperature was also the best anaerobic digestion agent because of the higher alkalinity (pH 11.51), better minerals content (P, K, Ca, Al) and larger than 100 m2/g surface area, all properties that are desirable for the improvement of stability, methane productivity and mitigation of CO2, H2S and free-NH3 in a digestion system.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20400 - Chemical engineering

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Energy Conversion and Management

ISSN

0196-8904

e-ISSN

—

Svazek periodika

277

Číslo periodika v rámci svazku

1 February 2023

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

12

Strana od-do

1-12

Kód UT WoS článku

000925133700001

EID výsledku v databázi Scopus

2-s2.0-85146081285