Molybdenum-leaching induced rapid surface reconstruction of amorphous/crystalline heterostructured trimetal oxides pre-catalyst for efficient water splitting and Zn-air batteries
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27710%2F23%3A10252887" target="_blank" >RIV/61989100:27710/23:10252887 - isvavai.cz</a>
Výsledek na webu
<a href="https://www.webofscience.com/wos/woscc/full-record/WOS:001007260000001" target="_blank" >https://www.webofscience.com/wos/woscc/full-record/WOS:001007260000001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ensm.2023.102806" target="_blank" >10.1016/j.ensm.2023.102806</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Molybdenum-leaching induced rapid surface reconstruction of amorphous/crystalline heterostructured trimetal oxides pre-catalyst for efficient water splitting and Zn-air batteries
Popis výsledku v původním jazyce
Crystalline and amorphous structure can entitle a catalyst with high stability and activity, respectively. Oxygen evolution reaction (OER) catalysts, which widely used in water electrolysis and rechargeable Zn-air batteries, often undergo a surface phase reconstruction process and generate amorphous active phases under applied anodic potential. Although widely known, few studies and strategies have been reported to rationally tune OER pre-catalysts for enhanced reaction kinetics. Herein, we report a trimetallic oxides (a/c-NiFeMoOx) OER per-catalyst with rationally tunable amorphous/crystalline heterostructure degrees by a precise-tuning component strategy. The best a/c-NiFeMoOx electrode exhibits an OER overpotential merely of 256 mV and a small cellvoltage of 1.52 V to reach 10 mA cm(-2) for water electrolysis, respectively. It is find that Mo leaching with tailored amorphous/crystalline heterostructure via the rational tuned degree of amorphousness promotes a rapid surface reconstruction of the a/c-NiFeMoOx pre-catalyst to form (oxy)hydroxide active species, whilst operando Raman, ex-situ X-ray photoelectron spectroscopy and density functional theory (DFT) analysis show the ample oxygen vacancies generated by phase transition significantly accelerates the deprotonation of OH* and lower the O* -> OOH* free energy for a fast oxygen evolution kinetics. Additionally, the practical application of a/c-NiFeMoOx cathode in rechargeable Zn-air battery delivers a robust long-term cycling (over 840 cycles).
Název v anglickém jazyce
Molybdenum-leaching induced rapid surface reconstruction of amorphous/crystalline heterostructured trimetal oxides pre-catalyst for efficient water splitting and Zn-air batteries
Popis výsledku anglicky
Crystalline and amorphous structure can entitle a catalyst with high stability and activity, respectively. Oxygen evolution reaction (OER) catalysts, which widely used in water electrolysis and rechargeable Zn-air batteries, often undergo a surface phase reconstruction process and generate amorphous active phases under applied anodic potential. Although widely known, few studies and strategies have been reported to rationally tune OER pre-catalysts for enhanced reaction kinetics. Herein, we report a trimetallic oxides (a/c-NiFeMoOx) OER per-catalyst with rationally tunable amorphous/crystalline heterostructure degrees by a precise-tuning component strategy. The best a/c-NiFeMoOx electrode exhibits an OER overpotential merely of 256 mV and a small cellvoltage of 1.52 V to reach 10 mA cm(-2) for water electrolysis, respectively. It is find that Mo leaching with tailored amorphous/crystalline heterostructure via the rational tuned degree of amorphousness promotes a rapid surface reconstruction of the a/c-NiFeMoOx pre-catalyst to form (oxy)hydroxide active species, whilst operando Raman, ex-situ X-ray photoelectron spectroscopy and density functional theory (DFT) analysis show the ample oxygen vacancies generated by phase transition significantly accelerates the deprotonation of OH* and lower the O* -> OOH* free energy for a fast oxygen evolution kinetics. Additionally, the practical application of a/c-NiFeMoOx cathode in rechargeable Zn-air battery delivers a robust long-term cycling (over 840 cycles).
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10400 - Chemical sciences
Návaznosti výsledku
Projekt
—
Návaznosti
V - Vyzkumna aktivita podporovana z jinych verejnych zdroju
Ostatní
Rok uplatnění
2023
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Energy Storage Materials
ISSN
2405-8297
e-ISSN
2405-8289
Svazek periodika
60
Číslo periodika v rámci svazku
Jun 2023
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
9
Strana od-do
—
Kód UT WoS článku
001007260000001
EID výsledku v databázi Scopus
—