Must the Best Laboratory Prepared Catalyst Also Be the Best in an Operational Application?

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27730%2F19%3A10242033" target="_blank" >RIV/61989100:27730/19:10242033 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989100:27710/19:10242033

Výsledek na webu

<a href="https://www.mdpi.com/2073-4344/9/2/160" target="_blank" >https://www.mdpi.com/2073-4344/9/2/160</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal9020160" target="_blank" >10.3390/catal9020160</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Must the Best Laboratory Prepared Catalyst Also Be the Best in an Operational Application?

Popis výsledku v původním jazyce

Three cobalt mixed oxide deN2O catalysts, with optimal content of alkali metals (K, Cs), were prepared on a large scale, shaped into tablets, and tested in a pilot plant reactor connected to the bypassed tail gas from the nitric production plant, downstream from the selective catalytic reduction of NOx by ammonia (SCR NOx/NH3) catalyst. High efficiency in N2O removal (N2O conversion of 75-90% at 450 oC, VHSV = 11,000 m3 mbed MINUS SIGN 3 h MINUS SIGN 1 ) was achieved. However, a different activity order of the commercially prepared catalyst tablets compared to the laboratory prepared catalyst grains was observed. Catalytic experiments in the kinetic regime using laboratory and commercial prepared catalysts and characterization methods (XRD, TPR-H2, physisorption, and chemical analysis) were utilized to explain this phenomenon. Experimentally determined internal effectiveness factors and their general dependency on kinetic constants were evaluated to discuss the relationship between the catalyst activity in the kinetic regime and the internal diffusion limitation in catalyst tablets as well as their morphology. The theoretical N2O conversion as a function of the intrinsic kinetic constants and diffusion rate, expressed as effective diffusion coefficients, was evaluated to estimate the final catalyst performance on a large scale and to answer the question of the above article title.

Název v anglickém jazyce

Must the Best Laboratory Prepared Catalyst Also Be the Best in an Operational Application?

Popis výsledku anglicky

Three cobalt mixed oxide deN2O catalysts, with optimal content of alkali metals (K, Cs), were prepared on a large scale, shaped into tablets, and tested in a pilot plant reactor connected to the bypassed tail gas from the nitric production plant, downstream from the selective catalytic reduction of NOx by ammonia (SCR NOx/NH3) catalyst. High efficiency in N2O removal (N2O conversion of 75-90% at 450 oC, VHSV = 11,000 m3 mbed MINUS SIGN 3 h MINUS SIGN 1 ) was achieved. However, a different activity order of the commercially prepared catalyst tablets compared to the laboratory prepared catalyst grains was observed. Catalytic experiments in the kinetic regime using laboratory and commercial prepared catalysts and characterization methods (XRD, TPR-H2, physisorption, and chemical analysis) were utilized to explain this phenomenon. Experimentally determined internal effectiveness factors and their general dependency on kinetic constants were evaluated to discuss the relationship between the catalyst activity in the kinetic regime and the internal diffusion limitation in catalyst tablets as well as their morphology. The theoretical N2O conversion as a function of the intrinsic kinetic constants and diffusion rate, expressed as effective diffusion coefficients, was evaluated to estimate the final catalyst performance on a large scale and to answer the question of the above article title.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20402 - Chemical process engineering

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

—

Svazek periodika

9

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

18

Strana od-do

160

Kód UT WoS článku

000460702200054

EID výsledku v databázi Scopus

—