Metal complexes as anticancer agent 2. Iron(III) and copper(II) bio-active complexes with benzylaminopurine derivatives.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F01%3A00001345" target="_blank" >RIV/61989592:15310/01:00001345 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Metal complexes as anticancer agent 2. Iron(III) and copper(II) bio-active complexes with benzylaminopurine derivatives.

Popis výsledku v původním jazyce

Iron(III) complexes with 2-(3-hydroxypropylamino )-6-benzylamino-9-isopropylpurine (Bohemin, HL1), in its protonized form, of the composition (H+HL1)2[FeCl5] # 2H2O (1), (H+HL1)2[FeCl5] # 3H2O (2) have been prepared by two different routes. A new way forsynthesis of copper(II) complex with 6-(2-ch1orobenzylarnino)purine (HL2), [Cu2(#-Cl)2(#-HL2)2(HL2)2Cl2] # 2H2O (3), together with the preparation of copper(II) complex with 6-(3-chlorobenzylarnino)purine (HL3), [Cu2(#-Cl)2(#-HL3)2Cl2] (4), is also reported. The characterization have been based on elemental analysis, electronic, infrared, ES + mass and 57Fe Mössbauer spectra, conductivity data and magnetic susceptibility temperature measurements over the 4.5-300 K for 1-3, and 35-300 K for 4, temperature range, respectively .Molecular structure of an electroneutral form of the HL3 ligand, (HL2 # 2H2O), and a protonized form of the HL3 ligand, (H+HL3-Cl), have been determined by a single-crystal X-ray analysis. A mononuclear trigonal-bi

Název v anglickém jazyce

Metal complexes as anticancer agent 2. Iron(III) and copper(II) bio-active complexes with benzylaminopurine derivatives.

Popis výsledku anglicky

Iron(III) complexes with 2-(3-hydroxypropylamino )-6-benzylamino-9-isopropylpurine (Bohemin, HL1), in its protonized form, of the composition (H+HL1)2[FeCl5] # 2H2O (1), (H+HL1)2[FeCl5] # 3H2O (2) have been prepared by two different routes. A new way forsynthesis of copper(II) complex with 6-(2-ch1orobenzylarnino)purine (HL2), [Cu2(#-Cl)2(#-HL2)2(HL2)2Cl2] # 2H2O (3), together with the preparation of copper(II) complex with 6-(3-chlorobenzylarnino)purine (HL3), [Cu2(#-Cl)2(#-HL3)2Cl2] (4), is also reported. The characterization have been based on elemental analysis, electronic, infrared, ES + mass and 57Fe Mössbauer spectra, conductivity data and magnetic susceptibility temperature measurements over the 4.5-300 K for 1-3, and 35-300 K for 4, temperature range, respectively .Molecular structure of an electroneutral form of the HL3 ligand, (HL2 # 2H2O), and a protonized form of the HL3 ligand, (H+HL3-Cl), have been determined by a single-crystal X-ray analysis. A mononuclear trigonal-bi

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

ED - Fyziologie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2001

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

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Svazek periodika

2001

Číslo periodika v rámci svazku

323

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

119-129

Kód UT WoS článku

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EID výsledku v databázi Scopus

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