Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]

Kód výsledku v IS VaVaI

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Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]

Popis výsledku v původním jazyce

Five new complexes of composition [Cu(dpt)Ni(CN)(4)] (1) (dpt = dipropylenetriamine), [Cu(dien)Ni(CN)(4)].2H(2)O (2) (dien = diethylenetriamine), [Cu(N,N'-dimeen)Ni(CN)(4)].H2O (3) (N,N' dimeen = N,N'-dimethylethylenediamine), [Cu(N,N dimeen)Ni(CN)(4)].H2O (4) (N,N-dimeen N,N dimethylethylenediamine) and [Cu(trimeen)Ni(CN)(4)] (5) (trimeen=N,N,N'-trimethylethylenediamine) have been obtained by the reactions of the mixture of Cu(ClO4)(2).6H(2)O, appropriate amine and K-2[Ni(CN)(4)] in water and have beencharacterized by IR and UV-Vis spectroscopies and magnetic measurements. The crystal structure of [Cu(dpt)Ni(CN)(4)] (1) has been determined by single-crystal X-ray analysis. The structure of 1 consists of a one-dimensional polymeric chain -Cu(dpt)-NC-Ni(CN)(2)-CN Cu(dpt)- in which the Cu(II) and Ni(11) atoms are linked by CN groups. The nickel atom is four coordinate with four cyanide carbon atoms (two cyano groups are terminal and two cyano groups (in cis fashion) are bridged) in a sq

Název v anglickém jazyce

Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)(4)]

Popis výsledku anglicky

Five new complexes of composition [Cu(dpt)Ni(CN)(4)] (1) (dpt = dipropylenetriamine), [Cu(dien)Ni(CN)(4)].2H(2)O (2) (dien = diethylenetriamine), [Cu(N,N'-dimeen)Ni(CN)(4)].H2O (3) (N,N' dimeen = N,N'-dimethylethylenediamine), [Cu(N,N dimeen)Ni(CN)(4)].H2O (4) (N,N-dimeen N,N dimethylethylenediamine) and [Cu(trimeen)Ni(CN)(4)] (5) (trimeen=N,N,N'-trimethylethylenediamine) have been obtained by the reactions of the mixture of Cu(ClO4)(2).6H(2)O, appropriate amine and K-2[Ni(CN)(4)] in water and have beencharacterized by IR and UV-Vis spectroscopies and magnetic measurements. The crystal structure of [Cu(dpt)Ni(CN)(4)] (1) has been determined by single-crystal X-ray analysis. The structure of 1 consists of a one-dimensional polymeric chain -Cu(dpt)-NC-Ni(CN)(2)-CN Cu(dpt)- in which the Cu(II) and Ni(11) atoms are linked by CN groups. The nickel atom is four coordinate with four cyanide carbon atoms (two cyano groups are terminal and two cyano groups (in cis fashion) are bridged) in a sq

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2001

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polyhedron

ISSN

0277-5387

e-ISSN

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Svazek periodika

20

Číslo periodika v rámci svazku

28

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

6

Strana od-do

3301-3306

Kód UT WoS článku

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EID výsledku v databázi Scopus

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