Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010165" target="_blank" >RIV/61989592:15310/09:00010165 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

Popis výsledku v původním jazyce

The following complexes [{Cu(ept)}(3) {Cr(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Cr(CN)(6))2]center dot 15H(2)O, [{Cu(hatce))(3){Cr(CN)(6)}(2)]center dot 14H(2)O,[{Cu(ept)}(3){Co(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Co(CN)(6)}(2)]center dot 18H(2)O and [{Cu(medpt)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo [13.3.1.1(6,10)]cicosane, hatco= 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6,9)]octadccane and medpt = N,N-bis-(3-aminopropyl) m ethyl amine) have been synthesized by the reactions Of Cu(ClO4)(2)center dot 6H(2)O or Cu(NO3)(2)center dot 3H(2)O and ept or medpt, or [Cu(hatce)](ClO4)(2)-2H(2)O and [Cu(hatco)Cl]ClO4 center dot H2O, and K-3[Cr(CN)(6)] or K-3[Co(CN)(6)] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal st

Název v anglickém jazyce

Hexacyanochromates(III) and Hexacyanocobaltates(III) of Copper(II) with Tridentate and Tetradentate N-donor Ligands. Crystal Structure of [{Cu(ept)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine)

Popis výsledku anglicky

The following complexes [{Cu(ept)}(3) {Cr(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Cr(CN)(6))2]center dot 15H(2)O, [{Cu(hatce))(3){Cr(CN)(6)}(2)]center dot 14H(2)O,[{Cu(ept)}(3){Co(CN)(6)}(2)]center dot 5H(2)O, [{Cu(hatce)}(3){Co(CN)(6)}(2)]center dot 18H(2)O and [{Cu(medpt)}(3){Co(CN)(6)}(2)]center dot H2O (ept = N-(2-aminoethyl)-1,3-propandiamine, hatce = 1,3,6,10,12,15-hexaazatricyclo [13.3.1.1(6,10)]cicosane, hatco= 1,3,6,9,11,14-hexaazatricyclo[12.2.1.1(6,9)]octadccane and medpt = N,N-bis-(3-aminopropyl) m ethyl amine) have been synthesized by the reactions Of Cu(ClO4)(2)center dot 6H(2)O or Cu(NO3)(2)center dot 3H(2)O and ept or medpt, or [Cu(hatce)](ClO4)(2)-2H(2)O and [Cu(hatco)Cl]ClO4 center dot H2O, and K-3[Cr(CN)(6)] or K-3[Co(CN)(6)] in aqueous solution, respectively. All the compounds have been characterized by elemental analyses, IR and UV-Vis spectroscopies and magnetic measurements and the three selected complexes were studied using thermal analysis. The crystal st

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2009

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polish Journal of Chemistry

ISSN

0137-5083

e-ISSN

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Svazek periodika

83

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

PL - Polská republika

Počet stran výsledku

10

Strana od-do

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Kód UT WoS článku

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EID výsledku v databázi Scopus

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