Synthesis of 2-chloro-N,N,N-trialkylethanaminium salts and related hydroxy-analogues as analytical standards for monitoring potential chemical warfare agent precursors

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F09%3A00010471" target="_blank" >RIV/61989592:15310/09:00010471 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis of 2-chloro-N,N,N-trialkylethanaminium salts and related hydroxy-analogues as analytical standards for monitoring potential chemical warfare agent precursors

Popis výsledku v původním jazyce

A set of choline related derivatives of 2-chloro-N,N,N-trialkylethanaminium salts N-substituted with simple alkyl groups such as methyl, ethyl, n-propyl and isopropyl has been prepared and characterized by the standard methods. Two methodologies based onthe alkylation reaction have been developed. The first one utilized the direct alkylation of 2-chloro-N,N-dialkylethanamines to afford the desired aminium salts. In cases where the first method failed the second alternative three-step methodology starting with the alkylation of the 2-(dialkylamino)ethanols was used. All these derivatives can be used as analytical standards for monitoring of potential chemical warfare agent precursors

Název v anglickém jazyce

Synthesis of 2-chloro-N,N,N-trialkylethanaminium salts and related hydroxy-analogues as analytical standards for monitoring potential chemical warfare agent precursors

Popis výsledku anglicky

A set of choline related derivatives of 2-chloro-N,N,N-trialkylethanaminium salts N-substituted with simple alkyl groups such as methyl, ethyl, n-propyl and isopropyl has been prepared and characterized by the standard methods. Two methodologies based onthe alkylation reaction have been developed. The first one utilized the direct alkylation of 2-chloro-N,N-dialkylethanamines to afford the desired aminium salts. In cases where the first method failed the second alternative three-step methodology starting with the alkylation of the 2-(dialkylamino)ethanols was used. All these derivatives can be used as analytical standards for monitoring of potential chemical warfare agent precursors

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2009

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Arkivoc

ISSN

1424-6376

e-ISSN

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Svazek periodika

2009

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

13

Strana od-do

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Kód UT WoS článku

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EID výsledku v databázi Scopus

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